Simultaneous Defect and Size Control of Metal-Organic Framework Nanostructures for Highly Efficient Carbon Dioxide Electroreduction to Multicarbon Products

被引:32
作者
Wang, Juan [1 ]
Liu, Jinjin [2 ]
Song, Yongqiao [1 ]
Geng, Shubo [2 ]
Peng, Zehua [3 ]
Yu, Jinli [1 ]
Liu, Fu [1 ]
Wang, Yunhao [1 ]
Xi, Shibo [4 ]
Zhang, Zhenjie [2 ]
Fan, Zhanxi [1 ,5 ,6 ]
机构
[1] City Univ Hong Kong, Dept Chem, Hong Kong 999077, Peoples R China
[2] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China
[3] City Univ Hong Kong, Dept Mech Engn, Hong Kong 999077, Peoples R China
[4] ASTAR, Inst Sustainabil Chem Energy & Environm, Singapore 627833, Singapore
[5] City Univ Hong Kong, Hong Kong Branch, Natl Precious Met Mat Engn Res Ctr NPMM, Hong Kong 999077, Peoples R China
[6] City Univ Hong Kong, Shenzhen Res Inst, Shenzhen 518057, Peoples R China
来源
ACS MATERIALS LETTERS | 2023年 / 5卷 / 08期
基金
中国国家自然科学基金;
关键词
CO2; ELECTROREDUCTION; ELECTROCHEMICAL REDUCTION; CATALYST; GROWTH; HYDROCARBONS; NUCLEATION; CONVERSION;
D O I
10.1021/acsmaterialslett.3c00567
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrocatalytic carbon dioxide (CO2) reductionreaction(CO2RR) has offered a sustainable approach in convertingan anthropogenic CO2 source to chemicals and fuels to promotecarbon neutral. However, it remains challenging to prepare high-performancecatalysts for efficient and selective CO2 electroreduction,especially toward the high-vaule multicarbon products. Here we reportthe facile synthesis of four kinds of nearly monodispersed CuTrz (HTrz= 1H,1,2,4-triazole) metal-organic framework(MOF) nanostructures with different sizes by controlling the reactionkinetics. Significantly, small CuTrz nanostructures demonstrate muchsuperior CO2RR performance over the large counterpartstoward multicarbon production in neutral electrolytes, with optimizedFaradaic efficiency of 55.4% and 81.8% for ethylene and multicarbonproducts, respectively. Detailed structural characterizations revealthat small CuTrz nanostructures are polycrystalline and rich in grainboundaries, while the large ones are single crystalline. This workhighlights the importance of simultaneous defect and size controlof MOFs in boosting their CO2RR performance for multicarbonproduction.
引用
收藏
页码:2121 / 2130
页数:10
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