Electrochemical deposition multi-walled carbon nanotube coatings on the surface of Ti6Al4V alloy for enhancing its biotribological properties

Ti6Al4V alloys have potential applications as bone implants. However, their poor biotribological performances affected the service life. In this work, carboxylic multi-walled carbon nanotubes (CMWNT) coatings were grafted on the surface of Ti6Al4V alloys by electrochemical deposition for enhancing the biotribological properties. The CMWNT coatings showed lower coefficient of friction and wear rates, with the reduction of wear rates of 6% in dry condition and 90% under simulated body fluid (SBF) lubrication. This result might be ascribed to the transfer of friction behavior from sliding friction to rolling friction. In addition, the tribological regularity of CMWNT coating with the frequency and load were discussed. Under dry friction, with the increase of frequency and the decrease of normal load, the COF of the CMWNT coating decreased. In SBF lubrication, the COF decreased and the wear rate increased with the increase of frequency. Moreover, the excellent anti-wear properties were observed at the below of 10 N. These findings indicate that the CMWNT coating has an excellent protective effect on titanium alloy, and has a certain application potential in the biomedical field.