Polyamides Derived from Terpenes: Advances in Their Synthesis, Characterization and Applications

被引:6
作者
Winnacker, Malte [1 ,2 ]
机构
[1] Tech Univ Munich, WACKER Chair Marcromol Chem, TUM Sch Nat Sci, Lichtenbergstr 4, D-85748 Garching, Germany
[2] Catalysis Res Ctr CRC, Ernst Otto Fischer Str 1, D-85748 Garching, Germany
关键词
bioeconomy; polyamides; ring-opening polymerization; sustainable polymers; terpenes; RING-OPENING COPOLYMERIZATION; SUSTAINABLE POLYMERS; LIMONENE OXIDE; THERMOPLASTIC ELASTOMERS; BIORENEWABLE POLYESTERS; ANIONIC-POLYMERIZATION; RENEWABLE RESOURCES; ALPHA-PINENE; POLYURETHANES; CHEMISTRY;
D O I
10.1002/ejlt.202300014
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Polyamides are very important polymers, with applications from commodities up to high-performance materials for, for example, fibers or for the biomedical sector. Nowadays, still most of them are synthesized from fossil resources. With regards to sustainability and bioeconomy, and especially regarding the new structures and properties that can thus be achieved, the preparation of polyamides (PAs) from natural precursors is getting more and more important. For this, especially the utilization of terpenes, a large and important group of natural products with different functions in nature (regulators, defense signals, etc.), is important, which is described herein. Similar approaches are interesting from a scientific point of view regarding, for example, structure-function-relations, but also with regards to different applications as, for example, high-performance or biomedical materials.Practical applications: Terpene-based polyamides can find many applications, from commodities up to high-performance fibers and special materials in (bio)medicine, for example, drug delivery, tissue engineering, etc.
引用
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页数:9
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共 135 条
[1]  
Abts, 2014, ULLMANNS ENCY IND CH
[2]   Polyurethane types, synthesis and applications - a review [J].
Akindoyo, John O. ;
Beg, M. D. H. ;
Ghazali, Suriati ;
Islam, M. R. ;
Jeyaratnam, Nitthiyah ;
Yuvaraj, A. R. .
RSC ADVANCES, 2016, 6 (115) :114453-114482
[3]   Green Chemistry: Principles and Practice [J].
Anastas, Paul ;
Eghbali, Nicolas .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :301-312
[4]   Stereocomplexed Poly(Limonene Carbonate): A Unique Example of the Cocrystallization of Amorphous Enantiomeric Polymers [J].
Auriemma, Finizia ;
De Rosa, Claudio ;
Di Caprio, Maria Rosaria ;
Di Girolamo, Rocco ;
Ellis, W. Chadwick ;
Coates, Geoffrey W. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (04) :1215-1218
[5]   Cyclic limonene dicarbonate as a new monomer for non-isocyanate oligo- and polyurethanes (NIPU) based upon terpenes [J].
Baehr, Moritz ;
Bitto, Alexandro ;
Muelhaupt, Rolf .
GREEN CHEMISTRY, 2012, 14 (05) :1447-1454
[6]   Sustainable Thermoplastic Elastomers from Terpene-Derived Monomers [J].
Bolton, Justin M. ;
Hillmyer, Marc A. ;
Hoye, Thomas R. .
ACS MACRO LETTERS, 2014, 3 (08) :717-720
[7]  
Breitmaier E., 2006, TERPENES FLAVORS FRA
[8]   Polymerization [J].
Carothers, WH .
CHEMICAL REVIEWS, 1931, 8 (03) :353-426
[9]   (+)-Limonene Functionalization: Syntheses, Optimization, and Scale-up Procedures for Sustainable Polymer Building Blocks [J].
Causero, Andrea ;
Troll, Carsten ;
Rieger, Bernhard .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (35) :15464-15477
[10]   Organocatalyzed Ring-Opening Polymerization of Cyclic Lysine Derivative: Sustainable Access to Cationic Poly(ε-lysine) Mimics [J].
Chen, Jinlong ;
Dong, Yilin ;
Xiao, Chunsheng ;
Tao, Youhua ;
Wang, Xianhong .
MACROMOLECULES, 2021, 54 (05) :2226-2231