Enhanced the energy storage performance of NBT-BY relaxor ferroelectric ceramics doped by STO

被引:10
|
作者
Chen, Gang [1 ,2 ]
Ji, Cong [1 ]
Bai, Xue [3 ]
Wang, Jie [1 ]
Chen, Chao [1 ]
Zhou, Zhijun [1 ]
Zhang, Zixuan [3 ]
Su, Zhengtan [1 ]
Gao, Rongli [1 ,2 ]
Cai, Wei [1 ,2 ]
Deng, Xiaoling [1 ,2 ]
Wang, Zhenhua [1 ,2 ]
Fu, Chunlin [1 ,2 ]
机构
[1] Chongqing Univ Sci & Technol, Sch Met & Mat Engn, Chongqing 401331, Peoples R China
[2] Chongqing Key Lab Nano Micro Composite Mat & Devic, Chongqing 401331, Peoples R China
[3] Chongqing Univ Sci & Technol, Sch Chem & Chem Engn, Chongqing 401331, Peoples R China
来源
关键词
Solid state reaction; Dielectric relaxation characteristics; Ferroelectric properties; Energy storage performance; DIELECTRIC-PROPERTIES; DENSITY; TEMPERATURE; MICROSTRUCTURE; EVOLUTION; SIZE;
D O I
10.1016/j.mtcomm.2023.106439
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
(1-x) (0.99 Na0.5Bi0.5TiO3-0.01BiYbO(3))-x SrTiO3 (abbreviated as (1-x) (0.99NBT-0.01BY)-x STO) (x = 0.1 similar to 0.4) relaxor ferroelectric ceramics were fabricated by a solid-state reaction method. The crystal structure, surface morphology as well as dielectric, ferroelectric and energy storage properties of (1-x) (0.99NBT-0.01BY)-x STO were investigated in detail. X-ray diffraction patterns show that NBT-BY-STO ceramics have a single perovskite structure with a pseudo-cubic phase. The introduction of STO can effectively refine the NBT-based ceramic grain. The relaxation behavior of NBT-BY can be enhanced by incorporating moderate STO, and the impedance reduced with the increase of STO content. The results of hysteresis loop analysis indicate that incorporating STO into NBT-BY contributes to an increase in the electric breakdown field and a reduction in remnant polarization, thus enhancing its energy storage performance significantly. A moderate energy storage property with large Wrec (similar to 2.5 J/cm(3)) and high. (similar to 80.97%) was achieved at 260 kV/cm for x = 0.4. Meanwhile, 0.98(0.99NBT-0.01BY) 0.2STO relaxor ferroelectric ceramic presented relatively good frequency and temperature stabilities of W-rec and eta. This work provides an effective strategy for enhancing the energy storage performance of NBT-based relaxor ferroelectric ceramics applied in pulsed power devices.
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页数:10
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