Photocatalytic, Intermolecular Olefin Alkylcarbofunctionalization Triggered by Haloalkyl Radicals Generated via Halogen Atom Transfer

被引：16

作者：

Singh, Tavinder ^{[1
]}

Nasireddy, Seshadri Reddy ^{[1
]}

Upreti, Ganesh Chandra ^{[1
]}

Arora, Shivani ^{[1
]}

Singh, Anand ^{[1
,2
]}

机构：

[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India

[2] Indian Inst Technol Kanpur, Dept Sustainable Energy Engn, Kanpur 208016, Uttar Pradesh, India

来源：

ORGANIC LETTERS | 2023年 / 25卷 / 30期

关键词：

REDOX-ACTIVE ESTERS; DIFUNCTIONALIZATION; ALKENES; ALKYL;

D O I：

10.1021/acs.orglett.3c01800

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A visible-light-mediated, haloalkyl-radical-initiated,three-componentolefin difunctionalization is reported. The application of haloalkylradicals generated via halogen atom abstraction by & alpha;-aminoalkylradicals has been demonstrated for accessing a new halogenated chemicalspace. Overall, the alkylcarbofunctionalization of styrenes was accomplishedby employing them as (poly)haloalkyl radical acceptors and subsequentC-C bond formation with quinoxalinones.

引用

页码：5558 / 5562

页数：5

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