Transition Metal-Catalyzed Synthesis of 1,2,3,4-Tetrasubstituted 1,3-Dienes from Propargylic Esters

被引：3

作者：

Dai, Mengfu ^{[1
]}

Kabandula, Lucy Felicity ^{[1
]}

Tai, Lanzhu ^{[1
]}

Wu, Boxue ^{[1
]}

Song, Liangliang ^{[2
]}

Chen, Liang-An ^{[1
]}

机构：

[1] Nanjing Normal Univ, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China

[2] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Int Innovat Ctr Forest Chem & Mat, Nanjing 210037, Peoples R China

来源：

CHEMCATCHEM | 2024年 / 16卷 / 14期

基金：

中国国家自然科学基金;

关键词：

Transition Metal; 1,3-Dienes; Propargylic Esters; Tetrasubstituted; Acyloxy Migration; CONTROLLED REGIODIVERGENT; ALPHA-PROPARGYLATION; CONJUGATED DIENES; ENYNE METATHESIS; CROSS-METATHESIS; EFFICIENT; ALKENES; NICKEL; ISOMERIZATIONS; REARRANGEMENT;

D O I：

10.1002/cctc.202301738

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transition metal-catalyzed synthesis of propargylic esters has been widely investigated, offering distinctive opportunities to build 1,3-diene skeletons. Access to 1,2,3,4-tetrasubstituted 1,3-dienes has been a longstanding challenge in organic synthesis due to a great diversity of stereoisomers from four substituents and unpredictable regioselectivity. Given the synthetic challenges and the importance, inventing methods for the generation of this valuable architecture has gathered much more attention. Recently, several intriguing works concerning this topic have been achieved towards the high regio- and stereoselective elaborate 1,2,3,4-tetrasubstituted 1,3-dienes. Herein, this concept summarizes recent advances in transition metal-catalyzed construction of 1,2,3,4-tetrasubstituted 1,3-dienes from propargylic esters and discusses the mechanism as well as their applications.

引用

页数：6

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