Reduction of vacancy defects induced by thermal annealing in β-Ga2O3 epilayer

被引:8
作者
Fan, Teng [1 ,2 ]
Tang, Ning [1 ,2 ,3 ,4 ]
Wei, Jiaqi [1 ,2 ]
Zhang, Shixiong [1 ,2 ]
Sun, Zhenhao [1 ,2 ]
Li, Guoping [1 ,2 ]
Jiang, Jiayang [1 ,2 ]
Fu, Lei [1 ,2 ]
Zhang, Yunfan [1 ,2 ]
Yuan, Ye [5 ]
Rong, Xin [1 ,2 ]
Ge, Weikun [1 ,2 ]
Wang, Xinqiang [1 ,2 ,3 ,4 ]
Shen, Bo [1 ,2 ,3 ,4 ]
机构
[1] Peking Univ, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China
[2] Peking Univ, Frontiers Sci Ctr Nanooptoelectron, Sch Phys, Beijing 100871, Peoples R China
[3] Peking Univ, Yangtze Delta Inst Optoelect, Nantong 226010, Jiangsu, Peoples R China
[4] Collaborat Innovat Ctr Quantum Matter, Beijing 100871, Peoples R China
[5] Songshan Lake Mat Lab, Dongguan 523808, Guangdong, Peoples R China
来源
MICRO AND NANOSTRUCTURES | 2023年 / 176卷
基金
中国国家自然科学基金;
关键词
beta-Ga2O3; Thermal annealing; Vacancy defects; GaO4; tetrahedra; PHOTOLUMINESCENCE; FABRICATION; PRESSURE; GA2O3; FILMS; BETA;
D O I
10.1016/j.micrna.2023.207525
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The effects of annealing in oxygen atmosphere of beta-Ga2O3 epilayers were investigated by X-ray photoelectron spectroscopy, photoluminescence and Fourier-transform infrared spectroscopy. The increasing proportions of Ga3+ and O-L (lattice oxygen) signifies the reduction of V-O as the annealing temperature rising. The variations of the photoluminescence emissions demonstrate the improvement of the crystal quality and reduction of V-O(1), V-O(2) and V-Ga. V-O and V-Ga are filled with oxygen atoms and gallium atoms after annealing, mainly attributed to the bonds con-structions of Ga (1)-O (1) and Ga (1)-O (2) in GaO4 tetrahedra. These results offer detailed in-formation and guidelines for removing intrinsic point defects in beta-Ga2O3.
引用
收藏
页数:9
相关论文
共 55 条
[1]   Growth Pressure Controlled Nucleation Epitaxy of Pure Phase ε- and β-Ga2O3 Films on Al2O3 via Metal-Organic Chemical Vapor Deposition [J].
Chen, Yuanpeng ;
Xia, Xiaochuan ;
Liang, Hongwei ;
Abbas, Qasim ;
Liu, Yang ;
Du, Guotong .
CRYSTAL GROWTH & DESIGN, 2018, 18 (02) :1147-1154
[2]   Microstructure, optical, and photoluminescence properties of β-Ga2O3 films prepared by pulsed laser deposition under different oxygen partial pressures [J].
Cui, Rui-Rui ;
Zhang, Jun ;
Luo, Zi-Jiang ;
Guo, Xiang ;
Ding, Zhao ;
Deng, Chao-Yong .
CHINESE PHYSICS B, 2021, 30 (02)
[3]   Effects of oxygen vacancies on the structural and optical properties of β-Ga2O3 [J].
Dong, Linpeng ;
Jia, Renxu ;
Xin, Bin ;
Peng, Bo ;
Zhang, Yuming .
SCIENTIFIC REPORTS, 2017, 7
[4]   Polaron crystallization and melting: Effects of the long-range Coulomb forces [J].
Fratini, S ;
Quemerais, P .
MODERN PHYSICS LETTERS B, 1998, 12 (24) :1003-1012
[5]   Self-trapped hole and impurity-related broad luminescence in β-Ga2O3 [J].
Frodason, Y. K. ;
Johansen, K. M. ;
Vines, L. ;
Varley, J. B. .
JOURNAL OF APPLIED PHYSICS, 2020, 127 (07)
[6]   Depth-resolved cathodoluminescence and surface photovoltage spectroscopies of gallium vacancies in β-Ga2O3 with neutron irradiation and forming gas anneals [J].
Gao, Hantian ;
Muralidharan, Shreyas ;
Karim, Md Rezaul ;
Cao, Lei R. ;
Leedy, Kevin D. ;
Zhao, Hongping ;
Rajan, Siddharth ;
Look, David C. ;
Brillson, Leonard J. .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2021, 39 (05)
[7]   Optical signatures of deep level defects in Ga2O3 [J].
Gao, Hantian ;
Muralidharan, Shreyas ;
Pronin, Nicholas ;
Karim, Md Rezaul ;
White, Susan M. ;
Asel, Thaddeus ;
Foster, Geoffrey ;
Krishnamoorthy, Sriram ;
Rajan, Siddharth ;
Cao, Lei R. ;
Higashiwaki, Masataka ;
Von Wenckstern, Holger ;
Grundmann, Marius ;
Zhao, Hongping ;
Look, David C. ;
Brillson, Leonard J. .
APPLIED PHYSICS LETTERS, 2018, 112 (24)
[8]   Growth and characterization of β-Ga2O3 thin films by molecular beam epitaxy for deep-UV photodetectors [J].
Ghose, Susmita ;
Rahman, Shafiqur ;
Hong, Liang ;
Rojas-Ramirez, Juan Salvador ;
Jin, Hanbyul ;
Park, Kibog ;
Klie, Robert ;
Droopad, Ravi .
JOURNAL OF APPLIED PHYSICS, 2017, 122 (09)
[9]   Organic additives assisted synthesis of mesoporous β-Ga2O3 nanostructures for photocatalytic dye degradation [J].
Girija, K. ;
Thirumalairajan, S. ;
Patra, Astam K. ;
Mangalaraj, D. ;
Ponpandian, N. ;
Viswanathan, C. .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2013, 28 (03)
[10]   Fabrication of β-Ga2O3 thin films and solar-blind photodetectors by laser MBE technology [J].
Guo, Daoyou ;
Wu, Zhenping ;
Li, Peigang ;
An, Yuehua ;
Liu, Han ;
Guo, Xuncai ;
Yan, Hui ;
Wang, Guofeng ;
Sun, Changlong ;
Li, Linghong ;
Tang, Weihua .
OPTICAL MATERIALS EXPRESS, 2014, 4 (05) :1067-1076