Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures

被引：1

作者：

Kazakov, A. I. ^{[1
]}

Yanovskiy, L. S. ^{[1
,2
,3
]}

Tomilov, Yu. V. ^{[4
]}

Molokanov, A. A. ^{[1
,3
]}

Plishkin, N. A. ^{[1
]}

Lempert, D. B. ^{[1
]}

Varlamova, N. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Chernogolovka 142432, Russia

[2] Natl Res Univ, Moscow Aviat Inst, Moscow 125310, Russia

[3] Natl Res Univ, Moscow Power Engn Inst, Moscow 111250, Russia

[4] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

PETROLEUM CHEMISTRY | 2023年 / 63卷 / 04期

关键词：

exo-tricyclo[5.2.1.0(2.6)]decane; exo; endo-tetracyclo[5.3.1.0(2,6).0(8,10)]undecane; thermal decomposition kinetics;

D O I：

10.1134/S0965544123030118

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.0(2.6)]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.0(2,6).0(8,10)]undecane (TCU-1, a monocyclo-propanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified.

引用

页码：468 / 476

页数：9

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