The depletion of conventional energy sources and associated environmental challenges drive the imperative shift towards renewable alternatives. Among these, solar energy emerges as a prominent, abundant, and cost-effective resource. This study introduces an innovative solar-driven multigeneration system, meticulously evaluated through energetic, exergetic, exergoeconomic, and exergo-environmental perspectives. The proposed system aims to concurrently generate power, produce heat, and yield hydrogen and freshwater for diverse applications. In a detailed case study, the system demonstrates a total output power of 14.86 MW, a freshwater production rate of 40.22 kg/s, and an energy efficiency of 19.81%. Exergy analysis reveals a total destruction of 81.48 MW, in which the parabolic trough solar collectors contribute to a significant share of 85.8%. The exergoeconomic assessment yields a payback period of 4.01 years, while the product exergo-environmental impact stands at 185.89 Pts/h. Also, the mass fraction of the high-temperature organic Rankine cycle has the main impact on the system's performance indexes. Furthermore, a comprehensive parametric study explores the impact of key design variables on system performance, employing a multi-objective particle swarm optimization algorithm and proper decision-maker to identify optimal operating conditions.