A rapid response room temperature hydrogen sensor based on a three-dimensional Pd-In2O3/rGO aerogel

被引:1
作者
Chen, Chunyan [1 ]
Liu, Yuheng [1 ]
Zhou, Jian [2 ]
He, Xuehu [1 ]
Chen, Chunlin [1 ]
Xiao, Guoqing [1 ,3 ,4 ]
Tang, Yaling [1 ]
Chen, Wanxin [1 ]
机构
[1] Southwest Petr Univ, Coll Chem & Chem Engn, Chengdu 610500, Sichuan, Peoples R China
[2] Key Lab Harmful Components & Tar Reduct Cigarette, Chengdu 610100, Sichuan, Peoples R China
[3] Oil & Gas Fire Protect Key Lab Sichuan Prov, Chengdu 611731, Sichuan, Peoples R China
[4] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
REDUCED GRAPHENE OXIDE; GAS-SENSING PROPERTIES; FUNCTIONALIZED GRAPHENE; PD NANOPARTICLES; NO2; COMPOSITE; SNO2; FABRICATION; FILMS; NANOCOMPOSITE;
D O I
10.1039/d3nj05894h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A three-dimensional (3D) Pd-In2O3/rGO aerogel was fabricated via a one-step hydrothermal treatment and freeze-drying. The morphology and structure of the 3D Pd-In2O3/rGO aerogel were examined. The aerogel material had a porous network structure, which was particularly advantageous for gas adsorption. The Pd-In2O3 nanoparticles were uniformly grown on the thin layer of rGO. The specific surface area of the aerogel and its rich pore structure inhibited aggregation and accumulation of the nanoparticles. Moreover, this structure facilitated the formation of a P-N heterogeneous structure, which ultimately enabled successful detection of hydrogen (H-2) at room temperature. The sensitivity for 10 000 ppm H-2 at room temperature was 27.66, and detection was stable and reproducible. Most notably, the response and recovery times for H-2 were as short as 11 and 13 seconds, respectively. The addition of a hydrogen-sensitive functional material to a reduced graphene oxide aerogel shows great promise for room temperature gas sensing.
引用
收藏
页码:5866 / 5876
页数:11
相关论文
共 43 条
  • [1] Gas-sensing properties of doped In2O3 films as sensors for NO2 in air
    Belysheva, TV
    Bogovtseva, LP
    Kazachkov, EA
    Serebryakova, NV
    [J]. JOURNAL OF ANALYTICAL CHEMISTRY, 2003, 58 (06) : 583 - 587
  • [2] Electrospinning of Pd-In2O3 Nanofibers for High-Performance Room Temperature Hydrogen Sensors
    Chen, Chunyan
    Chen, Wanxin
    Liu, Qian
    Liu, Yuheng
    Xiao, Guoqing
    Chen, Chunlin
    Li, Fangzhou
    Zhou, Jian
    [J]. ACS APPLIED NANO MATERIALS, 2022, 5 (09) : 12646 - 12655
  • [3] Three-Dimensional Crumpled Graphene-Based Nanosheets with Ultrahigh NO2 Gas Sensibility
    Chen, Zhuo
    Wang, Jinrong
    Umar, Ahmad
    Wang, Yao
    Li, Hao
    Zhou, Guofu
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (13) : 11819 - 11827
  • [4] Enhanced NO2 and SO2 sensor response under ambient conditions by polyol synthesized Ni doped SnO2 nanoparticles
    Das, Soumitra
    Girija, K. G.
    Debnath, A. K.
    Vatsa, R. K.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 854
  • [5] Three-dimensional reduced graphene oxide/cobaltosic oxide as a high-response sensor for triethylamine gas at room temperature
    Gao, Huijun
    Ma, Yuzhen
    Song, Peng
    Yang, Zhongxi
    Wang, Qi
    [J]. MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2021, 133
  • [6] Gas sensor based on rGO/ZnO aerogel for efficient detection of NO2 at room temperature
    Gao, Huijun
    Ma, Yuzhen
    Song, Peng
    Leng, Jinfeng
    Wang, Qi
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2021, 32 (08) : 10058 - 10069
  • [7] In2O3-graphene nanocomposite based gas sensor for selective detection of NO2 at room temperature
    Gu, Fubo
    Nie, Rui
    Han, Dongmei
    Wang, Zhihua
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2015, 219 : 94 - 99
  • [8] Near Room Temperature, Fast-Response, and Highly Sensitive Triethylamine Sensor Assembled with Au-Loaded ZnO/SnO2 Core Shell Nanorods on Flat Alumina Substrates
    Ju, Dian-Xing
    Xu, Hong-Yan
    Qiu, Zhi-Wen
    Zhang, Zi-Chao
    Xu, Oj
    Zhang, Jun
    Wang, Jie-Qiang
    Cao, Bing-Qiang
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (34) : 19163 - 19171
  • [9] Recent advances in carbon material-based NO2 gas sensors
    Lee, Sang Won
    Lee, Wonseok
    Hong, Yoochan
    Lee, Gyudo
    Yoon, Dae Sung
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2018, 255 : 1788 - 1804
  • [10] Three-Dimensional Mesoporous Graphene Aerogel-Supported SnO2 Nanocrystals for High-Performance NO2 Gas Sensing at Low Temperature
    Li, Lei
    He, Shuijian
    Liu, Minmin
    Zhang, Chunmei
    Chen, Wei
    [J]. ANALYTICAL CHEMISTRY, 2015, 87 (03) : 1638 - 1645