Cocoa quality: Chemical relationship of cocoa beans and liquors in origin identitation

被引:8
作者
Bagnulo, Eloisa [1 ]
Scavarda, Camilla [1 ]
Bortolini, Cristian [2 ]
Cordero, Chiara [1 ]
Bicchi, Carlo [1 ]
Liberto, Erica [1 ]
机构
[1] Univ Torino, Dipartimento Sci & Tecnol Farmaco, Turin, Italy
[2] Sremartec Italia Srl, Ferrero Grp, Ple P Ferrero 1, I-12051 Alba, CN, Italy
关键词
Quality; Cocoa beans and liquors; Origin identitation; Machine learning; Fingerprinting; Profiling; OF-THE-ART; FOOD AUTHENTICITY; CHOCOLATE; FLAVOR; AROMA; TECHNOLOGIES; FINGERPRINTS; CHALLENGES;
D O I
10.1016/j.foodres.2023.113199
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
In this study, HS-SPME-GC-MS was applied in combination with machine learning tools to the identitation of a set of cocoa samples of different origins. Untargeted fingerprinting and profiling approaches were tested for their informative, discriminative and classification ability provided by the volatilome of the raw beans and liquors inbound at the factory in search of robust tools exploitable for long-time studies. The ability to distinguish the country of origin on both beans and liquors is not so obvious due to processing steps accompanying the transformation of the beans, but this capacity is of particular interest to the chocolate industry as both beans and liquors can enter indifferently into the processing of chocolate. Both fingerprinting (untargeted) and profiling (targeted) strategies enable to decipher of the information contained in the complex dataset and the crossvalidation of the results, affording to discriminate between the origins with effective classification models.
引用
收藏
页数:8
相关论文
共 49 条
[1]   Making cocoa origin traceable: Fingerprints of chocolates using Flow Infusion - Electro Spray Ionization - Mass Spectrometry [J].
Acierno, Valentina ;
Alewijn, Martin ;
Zomer, Paul ;
van Ruth, Saskia M. .
FOOD CONTROL, 2018, 85 :245-252
[2]   Factors contributing to the variation in the volatile composition of chocolate: Botanical and geographical origins of the cocoa beans, and brand-related formulation and processing [J].
Acierno, Valentina ;
Yener, Sine ;
Alewijn, Martin ;
Biasioli, Franco ;
van Ruth, Saskia .
FOOD RESEARCH INTERNATIONAL, 2016, 84 :86-95
[3]   Flavor formation and character in cocoa and chocolate: A critical review [J].
Afoakwa, Emmanuel Ohene ;
Paterson, Alistair ;
Fowler, Mark ;
Ryan, Angela .
CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION, 2008, 48 (09) :840-857
[4]   Flavor Chemistry of Cocoa and Cocoa Products-An Overview [J].
Aprotosoaie, Ana Clara ;
Luca, Simon Vlad ;
Miron, Anca .
COMPREHENSIVE REVIEWS IN FOOD SCIENCE AND FOOD SAFETY, 2016, 15 (01) :73-91
[5]   To target or not to target? Definitions and nomenclature for targeted versus non-targeted analytical food authentication [J].
Ballin, Nicolai Zederkopff ;
Laursen, Kristian Hoist .
TRENDS IN FOOD SCIENCE & TECHNOLOGY, 2019, 86 :537-543
[6]  
Belitz HD., 2008, Food chemistry, DOI [10.1007/978-3-540-69934-7, DOI 10.1007/978-3-540-69934-7]
[7]   Poverty and climate change challenges for sustainable intensification of cocoa systems [J].
Boeckx, Pascal ;
Bauters, Marijn ;
Dewettinck, Koen .
CURRENT OPINION IN ENVIRONMENTAL SUSTAINABILITY, 2020, 47 :106-111
[8]   Chromatographic Fingerprinting Strategy to Delineate Chemical Patterns Correlated to Coffee Odor and Taste Attributes [J].
Bressanello, D. ;
Marengo, A. ;
Cordero, C. ;
Strocchi, G. ;
Rubiolo, P. ;
Pellegrino, G. ;
Ruosi, M. R. ;
Bicchi, C. ;
Liberto, E. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2021, 69 (15) :4550-4560
[9]   Chemometric Modeling of Coffee Sensory Notes through Their Chemical Signatures: Potential and Limits in Defining an Analytical Tool for Quality Control [J].
Bressanello, Davide ;
Liberto, Erica ;
Cordero, Chiara ;
Sgorbini, Barbara ;
Rubiolo, Patrizia ;
Pellegrino, Gloria ;
Ruosi, Manuela R. ;
Bicchi, Carlo .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2018, 66 (27) :7096-7109
[10]   Coffee aroma: Chemometric comparison of the chemical information provided by three different samplings combined with GC-MS to describe the sensory properties in cup [J].
Bressanello, Davide ;
Liberto, Erica ;
Cordero, Chiara ;
Rubiolo, Patrizia ;
Pellegrino, Gloria ;
Ruosi, Manuela R. ;
Bicchi, Carlo .
FOOD CHEMISTRY, 2017, 214 :218-226