Rhodium-catalyzed aminoacylation of alkenes via carbonylative C-H activation toward poly(hetero)cyclic alkylarylketones

被引：1
作者：
Yang, Chao [1 ,3 ]
Shi, Lijun [2 ]
Wang, Wenlong [1 ]
Xia, Ji-Bao [2 ]
Li, Fuwei [2 ]
机构：
[1] Dongguan Univ Technol, Sch Mat Sci & Engn, Dongguan 523808, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[3] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 04期
基金：
中国科学院西部之光基金; 中国国家自然科学基金;
关键词：
OXIDATIVE CARBONYLATION; PROPARGYL ALCOHOLS; COUPLING REACTIONS; BOND ACTIVATION; CARBON-MONOXIDE; CYCLIZATION; CYCLOADDITION; ANNULATION; INSERTION; AMINOCARBONYLATION;
D O I：
10.1039/d2qo01777f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The well-developed carbonylative synthesis of varied and useful complex molecules with CO is very efficient and attractive. Herein, rhodium-catalyzed modular carbonylative aminobenzoylation of alkenes with a pendant acylaniline enabled by dual cleavage of N-H bonds and C-H bonds under ambient pressure of CO/O-2 was developed. Various poly(hetero)cyclic alkylarylketones were obtained in moderate-to-high yields. The logical synthetic transformations of products were also explored.
引用
收藏
页码：872 / 879
页数：8
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