Polyoxometalate-based frameworks for photocatalysis and photothermal catalysis

被引：52
作者：
Chen, Xiaofei [1 ]
Wu, Hongzhuo [1 ]
Shi, Xinjian [1 ]
Wu, Lixin [2 ]
机构：
[1] Henan Univ, Natl & Local Joint Engn Res Ctr High Efficiency Di, Key Lab Special Funct Mat, Minist Educ, Kaifeng 475004, Peoples R China
[2] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
来源：
NANOSCALE | 2023年 / 15卷 / 21期
关键词：
METAL-ORGANIC FRAMEWORKS; CLUSTERS;
D O I：
10.1039/d3nr01176c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polyoxometalate-based frameworks (POM-based frameworks) are extended structures assembled from metal-oxide cluster units and organic frameworks that simultaneously possess the virtues of POMs and frameworks. They have been attracting immense attention because of their diverse architectures and charming topologies and also due to their probable application prospects in the areas of catalysis, separation, and energy storage. In this review, the recent progress in POM-based frameworks including POM-based metal organic frameworks (PMOFs), POM-based covalent organic frameworks (PCOFs), and POM-based supramolecular frameworks (PSFs) is systematically summarized. The design and construction of a POM-based framework and its application in photocatalysis and photothermal catalysis are introduced, respectively. Finally, our brief outlooks on the current challenges and future development of POM-based frameworks for photocatalysis and photothermal catalysis are provided.
引用
收藏
页码：9242 / 9255
页数：14
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