Halogen-bonded co-crystal containing 1,3-diiodoperchlorobenzene and the photoproduct rtct-tetrakis(pyridin-4-yl)cyclobutane resulting in a zigzag topology

被引：0

作者：

Bosch, Eric ^{[1
]}

Unruh, Daniel K. ^{[2
]}

Santana, Carlos L. ^{[3
]}

Groeneman, Ryan H. ^{[3
]}

机构：

[1] Missouri State Univ, Dept Chem & Biochem, Springfield, MO 65897 USA

[2] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA

[3] Webster Univ, Dept Biol Sci, St Louis, MO 63119 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷

关键词：

halogen bonding; organic solid state; co-crystal; photoproduct; cyclobutane; 2 + 2] cycloaddition reaction; zigzag network; SOLID-STATE; CYCLOBUTANE; ISOMERIZATION;

D O I：

10.1107/S2056989023001408

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The formation and crystal structure of a zigzag network held together by I center dot center dot center dot N halogen bonds is reported. In particular, the halogen-bond donor is 1,3-diiodoperchlorobenzene (C6I2Cl4) while the acceptor is the photoproduct rtct-tetrakis(pyridin-4-yl)cyclobutane (TPCB). Curiously, within the resulting co-crystal (C6I2Cl4)center dot(TPCB), the photoproduct accepts only two halogen bonds between neighbouring 4-pyridyl rings and as a result behaves as a bent twoconnected node rather than the expected four-connected centre. In addition, the photoproduct, TPCB, is also found to engage in C-H center dot center dot center dot N hydrogen bonds, forming an extended zigzag chain.

引用

页码：212 / +

页数：11

共 2 条

[1] Halogen-bonded zigzag molecular network based upon 1,2-diiodoperchlorobenzene and the photo-product rctt-1,3-bis(pyridin-4-yl)-2,4-diphenylcyclobutane
Dunning, Taylor J.
Bosch, Eric
Groeneman, Ryan H.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 506 - +
[2] Crystal structure and photoreactivity of a halogen-bonded cocrystal based upon 1,2-diiodoperchlorobenzene and 1,2-bis(pyridin-4-yl)ethylene
Bosch, Eric
Battle, Jessica D.
Groeneman, Ryan H.
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2020, 76 (557-561): : 557 - +

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