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Notable changes in geochemical and mineralogical characteristics of different phases of episyenitization: insights on the radioactive and shielding of the late phase
被引:5
|作者:
Taalab, Sherif A.
[1
]
Zakaly, Hesham M. H.
[2
,3
,4
]
Ivanov, V.
[4
]
Alrowaily, Albandari W.
[5
]
Awad, Hamdy A.
[6
]
Abed, Neveen S.
[7
]
Issa, Shams A. M.
[2
,8
]
Eltohamy, Amira M.
[7
]
Ene, Antoaneta
[9
]
机构:
[1] Al Azhar Univ, Fac Sci, Dept Geol, Cairo, Egypt
[2] Al Azhar Univ, Fac Sci, Dept Phys, Assiut Branch, Assiut, Egypt
[3] Istinye Univ, Fac Engn & Nat Sci, Comp Engn Dept, Istanbul, Turkiye
[4] Ural Fed Univ, Inst Phys & Technol, Yekaterinburg, Saudi Arabia
[5] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Phys, Riyadh, Saudi Arabia
[6] Al Azhar Univ, Fac Sci, Geol Dept, Assiut Branch, Assiut, Egypt
[7] Nucl Mat Author, Dept Geochem Explorat, Cairo, Egypt
[8] Univ Tabuk, Fac Sci, Dept Phys, Tabuk, Saudi Arabia
[9] Dunarea de Jos Univ Galati, Fac Sci & Environm, INPOLDE Res Ctr, Dept Chem Phys & Environm, Galati, Romania
关键词:
desilicified episyenite;
bazzite mineral;
isovalents;
radiation shielding applications;
dequartzification;
rare earth elements;
geochemistry;
Kab Amiri;
CENTRAL EASTERN DESERT;
URANIUM MOBILIZATION;
TRACE-ELEMENTS;
ZR-HF;
GRANITE;
FRACTIONATION;
METASOMATISM;
COMPLEXES;
EVOLUTION;
PATTERNS;
D O I:
10.3389/feart.2023.1241975
中图分类号:
P [天文学、地球科学];
学科分类号:
07 ;
摘要:
Kab Amiri granites are submitted to post-magmatic hydrothermal solutions through fracture and faults, causing several alteration processes. The most common processes are episyenitization, saussuritization, hematitization, sericitization, kaolinization, albitization, chloritization, silicification, and muscovitization. Kab Amiri granites are vuggy, with the vugs partially to completely refilled with new constituents. The least episyenitized granites have elevated amounts of Fe, P, Zr, Ni, U, Th, Ba, Y, Hf, Nb, and As, which are correlated with their mobilization from biotite, k-feldspar, plagioclase and metamict zircon. These elemental changes are related the partial albitization, muscovitization, desilicification and chloritizatiom, which lead to the mobilization of these elements and forming of specific mineral association in the least altered granites such as autonite, tripiolite, columbite, Zircon and galena. On the second stage, granites were subjected to intense alteration processes by mineralizing fluids, causing wholly muscovitization of biotite and feldspar, albitization of plagioclase, carbonitization and apatitization. Many elements were mobilized from these altered minerals, including Ti, Al, Mn, Mg, Ca, Na, K, Mo, Cu, Pb, Zn, Ag, Co, Sr, V, Cr, Sn, Rb, Ta, Li, Sc, W, S, In, and Tl, leading to definite mineralization as kaslite, monazite, xenotime, polycrase and apatite. The mineralizing fluids in the least and highly episyenitized granites are incorporated in some ore minerals like uranophane, fergusonite, bazzite and garnet. Notably, the presence of elements such as U, Th, and other heavy metals in Kab Amiri granites highlights the potential for these rocks in radiation shielding applications. The unique combination of elements and minerals resulting from the alteration processes can be leveraged for developing new materials or enhancing existing materials used in radiation shielding.
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