Effect of Quenching Method on the Structure of Glass Slag

被引：2

作者：

Hou, Yong ^{[1
,2
]}

Zhang, Shuo ^{[1
,2
]}

Zhang, Guohua ^{[3
,4
]}

Lv, Xuewei ^{[1
,2
]}

机构：

[1] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China

[2] Chongqing Univ, Chongqing Key Lab Vanadium Titanium Met & New Mat, Chongqing 400044, Peoples R China

[3] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China

[4] Univ Sci & Technol Beijing, Beijing Key Lab Green Recovery & Extract Rare & Pr, Beijing 100083, Peoples R China

来源：

TRANSACTIONS OF THE INDIAN INSTITUTE OF METALS | 2024年 / 77卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Raman spectroscopy; Slags; TEM; Crystals; crystallization; CRYSTALLIZATION KINETICS; SILICATE NETWORK; HIGH-TEMPERATURE; COOLING RATE; MOLD FLUXES; IN-SITU; MAS NMR; RAMAN; VISCOSITY; MICROSTRUCTURE;

D O I：

10.1007/s12666-023-03069-y

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Currently, the common way for structural investigation is to confirm the amorphous state of the quenched slag by XRD prior to Raman analysis. However, if the slag precipitates a few nanocrystals during quenching, XRD may not recognize them, but the slag structure has been changed. Therefore, this paper proposes to combine TEM with XRD and Raman for analyzing the slag structure and to verify it with blast furnace slag obtained by different quenching methods. The results show that the XRD curves of the slags obtained by quenching in water or on a stainless steel plate show amorphous states, but the deconvolution results of Raman spectra are significantly different. The TEM analysis finds a few crystals in the slag obtained by the latter, which is responsible for the structural differences. Therefore, it is necessary to confirm the amorphous state of the slag by both XRD and TEM before studying the structure.

引用

页码：127 / 131

页数：5

共 26 条

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