Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)

被引：4

作者：

Cruz-Navarro, Jesus Antonio ^{[1
]}

Sanchez-Mora, Arturo ^{[1
]}

Serrano-Garcia, Juan S. ^{[1
]}

Amaya-Florez, Andres ^{[1
]}

Colorado-Peralta, Raul ^{[2
]}

Reyes-Marquez, Viviana ^{[3
]}

Morales-Morales, David ^{[1
]}

Fernandez-Alvarez, Francisco J.

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Ciudad Univ,Circuito Exterior S-N, Ciudad De Mexico 04510, Mexico

[2] Univ Veracruzana, Fac Ciencias Quim, Prolongac Oriente 6 1009, Orizaba 94340, Veracruz, Mexico

[3] Univ Sonora, Dept Ciencias Quim Biol, Luis Encinas & Rosales S-N, Hermosillo 83000, Sonora, Mexico

来源：

CATALYSTS | 2024年 / 14卷 / 01期

关键词：

earth-abundant transition metals; catalysis; pincer complexes; cross-coupling reactions; KUMADA-TAMAO-CORRIU; LIGAND COOPERATION; GRIGNARD-REAGENTS; OPTICAL-PROPERTIES; ALKYL-HALIDES; ARYL HALIDES; PALLADIUM; NICKEL; SUZUKI; AMINES;

D O I：

10.3390/catal14010069

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The increase of noble-metal-free catalysis in organic chemistry is a trending topic in constant growth due to the price increase of noble metals and their scarce abundance. As a result, many earth-abundant transition-metal complexes containing nickel, iron, or cobalt have been successfully applied in the homogeneous catalysis of a wide number of cross-coupling reactions, and the use of pincer complexes based on these earth-abundant metals was recently explored, affording interesting results. Thus, this review provides a general overview of earth-abundant 3D pincer complexes and their application during the last decade as catalysts in cross-coupling reactions such as Kumada-Corriu, Suzuki-Miyaura, Sonogashira, C-S cross-coupling, and C-N bond-forming reactions.

引用

页数：23

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