Ni-Catalyzed Asymmetric C-P Cross-Coupling Reaction for the Synthesis of Chiral Heterocyclic Phosphine Oxides

被引：14

作者：

Cui, Ranran ^{[1
]}

Wang, Yinqi ^{[1
]}

Yuwen, Liyan ^{[1
]}

Gao, Li ^{[1
]}

Huang, Zhuo ^{[1
]}

Wang, Wei-Han ^{[1
]}

Zhang, Qing-Wei ^{[1
]}

机构：

[1] Univ Sci & Technol China, Key Lab Precis & Intelligent Chem, Dept Chem, Hefei 230026, Peoples R China

来源：

ORGANIC LETTERS | 2023年

关键词：

MECHANISTIC IMPLICATIONS; NICKEL CATALYSIS; CARBON; PHOSPHORYLATION; DERIVATIVES; ARYLATION; LIGHT;

D O I：

10.1021/acs.orglett.3c02216

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nickelperforms excellently in C-C and C-X cross-couplingreactions. Here, we disclose a Ni(II)-catalyzed asymmetric C-Pcross-coupling reaction to afford valuable chiral heterocyclic tertiaryphosphine oxides. The method is mild and efficient, which invokesa self-sustained nickel catalytic cycle without an external reductant,light irradiation, or electricity.

引用

页码：6139 / 6142

页数：4

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