A New Approach to the Ring-Opening of Epoxides under Mild and Green Conditions

被引：0
|
作者：
Ataee-Najari, Ali Reza [1 ]
Zarei, Mahmoud [2 ]
Ahmadi, Hossein [1 ]
Zolfigol, Mohammad Ali [1 ]
Ghorbani-Choghamarani, Arash [1 ]
Hosseinifard, Mojtaba [3 ]
机构：
[1] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, POB 6517838683, Hamadan, Iran
[2] Univ Qom, Fac Sci, Dept Chem, Qom 37185359, Iran
[3] Mat & Energy Res Ctr, Dept Energy, Karaj, Iran
来源：
POLYCYCLIC AROMATIC COMPOUNDS | 2024年 / 44卷 / 05期
基金：
美国国家科学基金会;
关键词：
& alpha; -Aryloxy alcohols; Bronsted-acid catalyst; ring-opening of epoxide; metal-organic frameworks; Zr-UiO-66-CO2H]Br; METAL-ORGANIC FRAMEWORKS; EFFICIENT CATALYST; ACETIC-ACID; N-HETEROCYCLE; ALCOHOLS; NANOPARTICLES; THIOLYSIS; BROMIDE; DERIVATIVES; CONVERSION;
D O I：
10.1080/10406638.2023.2235055
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this research work, we have designed and introduced [Zr-UiO-66-CO2H]Br as a versatile heterogeneous acid catalyst for the ring-opening of epoxides through S(N)1 and/or S(N)2 type mechanisms. In addition, the appropriate method for designing an active and efficient Bronsted acid site in metal-organic frameworks is discussed. [Zr-UiO-66-CO2H]Br was applied for the preparation of a-aryloxy alcohols by the condensation reaction of various epoxides with phenol or thiophenols under mild and green conditions.{GRAPHIACAL ABSTRACT}
引用
收藏
页码：3442 / 3455
页数：14
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