A New Approach to the Ring-Opening of Epoxides under Mild and Green Conditions

被引：0

作者：

Ataee-Najari, Ali Reza ^{[1
]}

Zarei, Mahmoud ^{[2
]}

Ahmadi, Hossein ^{[1
]}

Zolfigol, Mohammad Ali ^{[1
]}

Ghorbani-Choghamarani, Arash ^{[1
]}

Hosseinifard, Mojtaba ^{[3
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, POB 6517838683, Hamadan, Iran

[2] Univ Qom, Fac Sci, Dept Chem, Qom 37185359, Iran

[3] Mat & Energy Res Ctr, Dept Energy, Karaj, Iran

来源：

POLYCYCLIC AROMATIC COMPOUNDS | 2024年 / 44卷 / 05期

基金：

美国国家科学基金会;

关键词：

& alpha; -Aryloxy alcohols; Bronsted-acid catalyst; ring-opening of epoxide; metal-organic frameworks; Zr-UiO-66-CO2H]Br; METAL-ORGANIC FRAMEWORKS; EFFICIENT CATALYST; ACETIC-ACID; N-HETEROCYCLE; ALCOHOLS; NANOPARTICLES; THIOLYSIS; BROMIDE; DERIVATIVES; CONVERSION;

D O I：

10.1080/10406638.2023.2235055

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this research work, we have designed and introduced [Zr-UiO-66-CO2H]Br as a versatile heterogeneous acid catalyst for the ring-opening of epoxides through S(N)1 and/or S(N)2 type mechanisms. In addition, the appropriate method for designing an active and efficient Bronsted acid site in metal-organic frameworks is discussed. [Zr-UiO-66-CO2H]Br was applied for the preparation of a-aryloxy alcohols by the condensation reaction of various epoxides with phenol or thiophenols under mild and green conditions.{GRAPHIACAL ABSTRACT}

引用

页码：3442 / 3455

页数：14

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