Study of activation methods for Ortho-para hydrogen catalysts in a small isothermal converter based on gas chromatography at LN2 temperature

被引:8
作者
Zhou, Han [1 ,2 ]
Li, Zhengyu [1 ]
Li, Mengshi [4 ]
He, Ming [1 ]
Wu, Qi [1 ,2 ]
Gong, Linghui [1 ,3 ]
机构
[1] Chinese Acad Sci, Tech Inst Chem & Phys, Res Ctr Cryogen Engn & Syst, Beijing 100089, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
[3] Zhongshan Inst Adv Cryogen Technol, Zhongshan 528455, Guangdong, Peoples R China
[4] Peking Univ, Sch Publ Hlth, Dept Maternal & Child Hlth, Beijing 100191, Peoples R China
关键词
Ortho-parahydrogen conversion; Ortho-parahydrogen catalysts; Activation conditions; Experimental studies; Multiple linear regression; GOLD NANOPARTICLES; SPIN CONVERSION; ORTHOHYDROGEN; MECHANISM; ENERGY; PARAHYDROGEN; SEPARATION;
D O I
10.1016/j.ijhydene.2023.10.155
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The efficiency of the O-P catalyst activation directly affects how long liquid hydrogen may be kept. The ideal O-P catalyst activation condition must therefore be investigated. In this study, the effects of activation temperature, activation duration, and activation methods on the catalytic efficiency of a commercial O-P catalyst were thoroughly evaluated experimentally. We assessed the O-P catalysts' catalytic performance under richer activation conditions compared with previous studies. We also employed multiple linear regression to analyze the effects of the aforementioned experimental factors based on our experimental data. Results suggest that O-P catalyst for industrial applications should be activated at 160 degrees C for 8-12 h while being constantly vacuumed. We also found that the activation temperature had the largest influence on the catalytic performance of O-P catalyst. The pertinent experimental findings from this investigation provide a reference for the development and use of Ortho-Para hydrogen converters in hydrogen liquefiers.
引用
收藏
页码:55 / 64
页数:10
相关论文
共 49 条
[1]   Hydrogen energy, economy and storage: Review and recommendation [J].
Abe, J. O. ;
Popoola, A. P. I. ;
Ajenifuja, E. ;
Popoola, O. M. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (29) :15072-15086
[2]   SEPARATION + ANALYSIS OF VARIOUS FORMS OF HYDROGEN BY ADSORPTION + GAS CHROMATOGRAPHY [J].
AKHTAR, S ;
SMITH, HA .
CHEMICAL REVIEWS, 1964, 64 (03) :261-&
[3]   A discharge investigation of hydrogen and deuterium atom formation, and parahydrogen and orthodeuterium reconversion [J].
Andrews, L ;
Wang, XF .
JOURNAL OF CHEMICAL PHYSICS, 2004, 121 (10) :4724-4729
[4]   HYDROGEN - THE OPTIMUM CHEMICAL FUEL [J].
不详 .
APPLIED ENERGY, 1994, 47 (2-3) :183-199
[5]  
[Anonymous], 1964, Technology and uses of liquid hydrogen
[6]   GAS-CHROMATOGRAPHIC SEPARATION OF ORTHOHYDROGEN AND PARAHYDROGEN ON MOLECULAR SIEVES - ANALYSIS, PREPARATION, AND MEASUREMENT OF CATALYTIC CONVERSION AND OF ADSORPTION [J].
BACHMANN, L ;
BECHTOLD, E ;
CREMER, E .
JOURNAL OF CATALYSIS, 1962, 1 (02) :113-120
[7]   Future aircraft concept in terms of energy efficiency and environmental factors [J].
Baharozu, Eren ;
Soykan, Gurkan ;
Ozerdem, Baris .
ENERGY, 2017, 140 :1368-1377
[8]   Comprehensive investigation on hydrogen and fuel cell technology in the aviation and aerospace sectors [J].
Baroutaji, Ahmad ;
Wilberforce, Tabbi ;
Ramadan, Mohamad ;
Olabi, Abdul Ghani .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2019, 106 :31-40
[9]  
Barrick P.L., 1965, Improved Ferric Oxide Gel Catalysts for Ortho-Parahydrogen Conversion, P181
[10]   History of gas chromatography [J].
Bartle, KD ;
Myers, P .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2002, 21 (9-10) :547-557