Assessment of kinetic models for the production of γ-valerolactone developed in isothermal, adiabatic and isoperibolic conditions

被引:3
作者
Salcedo, Wenel Naudy Vasquez [1 ,2 ]
Mignot, Melanie
Renou, Bruno [2 ,3 ]
Leveneur, Sebastien [1 ]
机构
[1] Normandie Univ, INSA Rouen Normandie, UNIROUEN, LSPC,UR4704, F-76000 Rouen, France
[2] Normandie Univ, INSA Rouen, UNIROUEN, CNRS,CORIA, F-76000 Rouen, France
[3] Normandie Univ, COBRA Lab, INSA Rouen, UNIROUEN,CNRS, F-76000 Rouen, France
关键词
Kinetic modeling; Gamma valerolactone; Levulinate; Calorimetry; Adiabatic; LEVULINIC ACID HYDROGENATION; CATALYTIC TRANSFER HYDROGENATION; THERMAL RISK-ASSESSMENT; GAMMA-VALEROLACTONE; FORMIC-ACID; SELECTIVE HYDROGENATION; METHYL LEVULINATE; METAL-CATALYSTS; BIOMASS; CONVERSION;
D O I
10.1016/j.fuel.2023.128792
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The use of lignocellulosic biomass as raw materials for the production of biofuels is increasing. There are several potential processes valorizing these raw materials, but the shift from lab-scale to industrial scale requires the development of reliable and robust kinetic models. Usually, these models are developed in isothermal mode, limiting their use for thermal risk assessment or pinch analysis. We developed and assessed several kinetic models for the hydrogenation of butyl levulinate to & gamma;-valerolactone over Ru/C in different thermal modes, i.e., isothermal, isoperibolic and adiabatic modes. The reaction calorimeter Mettler-Toledo RC1 was used to perform kinetic experiments. Bayesian inference was used during the regression stage to calculate the credible intervals. The validation stage was done by a holdout method. From the regression and validation stage, we found that the non-competitive Langmuir Hinshelwood with hydrogen non-dissociation and dissociation were the most reliable models. These models can predict the kinetics of this reaction system in different thermal modes.
引用
收藏
页数:12
相关论文
共 105 条
  • [1] Analysis of Kinetics and Reaction Pathways in the Aqueous-Phase Hydrogenation of Levulinic Acid To Form γ-Valerolactone over Ru/C
    Abdelrahman, Omar Ali
    Heyden, Andreas
    Bond, Jesse Q.
    [J]. ACS CATALYSIS, 2014, 4 (04): : 1171 - 1181
  • [2] A critical review on suitability and catalytic production of butyl levulinate as a blending molecule for green diesel
    Ahmad, Khwaja Alamgir
    Siddiqui, Mohammad Haider
    Pant, Kamal K.
    Nigam, K. D. P.
    Shetti, Nagaraj P.
    Aminabhavi, Tejraj M.
    Ahmad, Ejaz
    [J]. CHEMICAL ENGINEERING JOURNAL, 2022, 447
  • [3] Sustainable Continuous Flow Valorization of γ-Valerolactone with Trioxane to α-Methylene-γ-Valerolactone over Basic Beta Zeolites
    Al-Naji, Majd
    Puertolas, Begona
    Kumru, Baris
    Cruz, Daniel
    Baeumel, Marius
    Schmidt, Bernhard V. K. J.
    Tarakina, Nadezda, V
    Perez-Ramirez, Javier
    [J]. CHEMSUSCHEM, 2019, 12 (12) : 2628 - 2636
  • [4] Exploring the ruthenium catalysed synthesis of γ-valerolactone in alcohols and utilisation of mild solvent-free reaction conditions
    Al-Shaal, Mohammad G.
    Wright, William R. H.
    Palkovits, Regina
    [J]. GREEN CHEMISTRY, 2012, 14 (05) : 1260 - 1263
  • [5] Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass
    Alonso, David Martin
    Wettstein, Stephanie G.
    Dumesic, James A.
    [J]. GREEN CHEMISTRY, 2013, 15 (03) : 584 - 595
  • [6] Alonso DM, 2013, ENERG ENVIRON SCI, V6, P76, DOI [10.1039/C2EE23617F, 10.1039/c2ee23617f]
  • [7] Catalytic conversion of biomass to biofuels
    Alonso, David Martin
    Bond, Jesse Q.
    Dumesic, James A.
    [J]. GREEN CHEMISTRY, 2010, 12 (09) : 1493 - 1513
  • [8] Commercialization of biofuel products: A systematic literature review
    Amerit, Bosco
    Ntayi, Joseph M.
    Ngoma, Muhammed
    Bashir, Hassan
    Echegu, Simon
    Nantongo, Maria
    [J]. RENEWABLE ENERGY FOCUS, 2023, 44 : 223 - 236
  • [9] Hydrogenation of the pivotal biorefinery platform molecule levulinic acid into renewable fuel γ-valerolactone catalyzed by unprecedented highly active and stable ruthenium nanoparticles in aqueous media
    Anagnostopoulou, Eleni
    Lilas, Panagiotis
    Diamantopoulou, Perikleia
    Fakas, Christos
    Krithinakis, Ioannis
    Patatsi, Eleni
    Gabrielatou, Elpida
    van Muyden, Antoine P.
    Dyson, Paul J.
    Papadogianakis, Georgios
    [J]. RENEWABLE ENERGY, 2022, 192 : 35 - 45
  • [10] Batch salicylic acid nitration by nitric acid/acetic acid mixture under isothermal, isoperibolic and adiabatic conditions
    Andreozzi, R.
    Canterino, M.
    Caprio, V.
    Di Somma, I.
    Sanchirico, R.
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2006, 138 (03) : 452 - 458