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Removal of levofloxacin and ciprofloxacin from aqueous solutions and an economic evaluation using the electrocoagulation process
被引:35
|作者:
Mohammed, Sabah J.
[1
]
M-Ridha, Mohanad Jasim
[1
]
Abed, Khalid M.
[2
,3
]
Elgharbawy, Amal A. M.
[4
,5
]
机构:
[1] Univ Baghdad, Coll Engn, Dept Environm Engn, Baghdad, Iraq
[2] Univ Baghdad, Coll Engn, Dept Chem Engn, Baghdad, Iraq
[3] Univ Malaya, Dept Chem Engn, Fac Engn, Kuala Lumpur, Malaysia
[4] Int Islamic Univ Malaysia, Int Inst Halal Res & Training INHART, Kuala Lumpur, Malaysia
[5] Int Islamic Univ Malaysia, Dept Biotechnol Engn, Bioenvironm Engn Res Ctr BERC, Fac Engn, Kuala Lumpur, Malaysia
关键词:
Antibiotics;
stainless steel electrodes;
economic evaluation;
kinetic models;
isotherm models;
wastewater treatment;
WASTE-WATER;
ADSORPTION;
DYE;
DECOLORIZATION;
OXIDATION;
CARBON;
TETRACYCLINE;
CHROMIUM(VI);
PRODUCTS;
FLUORIDE;
D O I:
10.1080/03067319.2021.1913733
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
For this research, the utilisation of electrocoagulation (EC) toremove theciprofloxacin (CIP) and levofloxacin (LVX) from aqueous solutions was examined. The effective removal efficiencies are 93.47% for CIP and 88.00% for LVX, under optimum conditions. The adsorption isotherm models with suitable mechanisms were applied to determine the elimination of CIP and LVX utilizingtheEC method. Thefindingsshowed the adsorption of CIP and LVX on iron hydroxide flocs followed the Sips isotherm, with correlation coefficient values (R-2) of 0.939 and 0.937. Threekinetic models were reviewed to determine the accurate CIP and LVX elimination methods using the EC method. The results showed that itfittedfor the second-order model, which indicated that the chemical adsorption mechanism controlled the removal of CIP and LVX. The R-2 with CIP is 0.944, and LVX is 0.941. For binary system removal, efficiencies were 93.00, 90.10, and 96.30% for CIP, and 91.80, 96.10, and 92.97% for LVX, at the CIP ratio: LVX of 1:1, 1:4, and 4:1. The electrode consumption (ELC) and electrical energy consumption (EEC) were found at 0.208 g and 3.21 kWh(-3) for a single operation. The operating cost was estimated at 0.613 US$ m(-3).
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页码:3801 / 3819
页数:19
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