Deep eutectic solvents as an emerging green platform for the synthesis of functional materials

被引:45
作者
Ma, Yunping [1 ]
Yang, Yu [1 ]
Li, Tie [2 ]
Hussain, Shahid [1 ]
Zhu, Maiyong [1 ]
机构
[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
[2] Suzhou Inst Nanotech & Nanob SINANO, Chinese Acad Sci CAS, I Lab, 398 Ruoshui Rd, Suzhou 215123, Peoples R China
关键词
ONE-POT SYNTHESIS; HIERARCHICALLY POROUS CARBON; SUSTAINABLE SOLVENTS; GOLD NANOPARTICLES; COLLOIDAL SILVER; HIGHLY EFFICIENT; IONIC LIQUIDS; PERFORMANCE; GRAPHENE; EXTRACTION;
D O I
10.1039/d3gc04289h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As a multifunctional solvent, deep eutectic solvents (DESs) have numerous potential applications in a variety of fields due to their low vapor pressure, tunability, environmental friendliness, and the ability to dissolve a wide range of chemicals. DESs serve as solvents, templates, and functionalization agents, among other functions, in the synthesis of functional materials, all of which are covered in this work. In addition, recent developments in the creation of different functional materials utilizing DESs are reviewed, as is the mechanism of DES activity throughout the preparation process and their potential to control the material's characteristics. The inherent features, cost-effectiveness, and environmental friendliness of DESs are highlighted in the study, and it is argued that this makes them a potential green platform. Finally, the potential, key problems, and limitations of DESs are outlined for use in materials science. It is anticipated that this study will be a resource for proponents and users of green chemistry, assisting them in reducing pollution, boosting productivity, and reaping the rewards of progress in the development of DESs. Deep eutectic solvents (DESs) enable many processes to be environmentally friendly. This Tutorial Review aims to showcase the roles of DESs in the synthesis of functional materials from a green chemistry perspective.
引用
收藏
页码:3627 / 3669
页数:43
相关论文
共 226 条
  • [1] Selective Oxidation of Alcohols through Fe3O4@SiO2/K2CO3-Glycerin Deep Eutectic Solvent as a Heterogeneous Catalytic System
    Abbasi, Sepideh
    Reza Naimi-Jamal, Mohammad
    Javanshir, Shahrzad
    Heydari, Akbar
    [J]. CHEMISTRYOPEN, 2022, 11 (12)
  • [2] Eutectic-based ionic liquids with metal-containing anions and cations
    Abbott, Andrew P.
    Barron, John C.
    Ryder, Karl S.
    Wilson, David
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (22) : 6495 - 6501
  • [3] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids
    Abbott, AP
    Boothby, D
    Capper, G
    Davies, DL
    Rasheed, RK
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) : 9142 - 9147
  • [4] Novel solvent properties of choline chloride/urea mixtures
    Abbott, AP
    Capper, G
    Davies, DL
    Rasheed, RK
    Tambyrajah, V
    [J]. CHEMICAL COMMUNICATIONS, 2003, (01) : 70 - 71
  • [5] Phytotreatment of soil contaminated with used lubricating oil using Hibiscus cannabinus
    Abioye, O. P.
    Agamuthu, P.
    Aziz, A. R. Abdul
    [J]. BIODEGRADATION, 2012, 23 (02) : 277 - 286
  • [6] Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES
    Abranches, Dinis O.
    Martins, Monia A. R.
    Silva, Liliana P.
    Schaeffer, Nicolas
    Pinho, Simao P.
    Coutinho, Joao A. P.
    [J]. CHEMICAL COMMUNICATIONS, 2019, 55 (69) : 10253 - 10256
  • [7] Batch and Flow Nanomanufacturing of Large Quantities of Colloidal Silver and Gold Nanocrystals Using Deep Eutectic Solvents
    Adhikari, Laxmi
    Larm, Nathaniel E.
    Baker, Gary A.
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (39): : 14679 - 14689
  • [8] Argentous Deep Eutectic Solvent Approach for Scaling Up the Production of Colloidal Silver Nanocrystals
    Adhikari, Laxmi
    Larm, Nathaniel E.
    Baker, Gary A.
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (13) : 11036 - 11043
  • [9] Rapid Microwave-Assisted Synthesis of Silver Nanoparticles in a Halide-Free Deep Eutectic Solvent
    Adhikari, Laxmi
    Larm, Nathaniel E.
    Bhawawet, Nakara
    Baker, Gary A.
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (05): : 5725 - 5731
  • [10] Well-controlled in-situ growth of 2D WO3 rectangular sheets on reduced graphene oxide with strong photocatalytic and antibacterial properties
    Ahmed, Bilal
    Ojha, Animesh K.
    Singh, Ajeet
    Hirsch, Florian
    Fischer, Ingo
    Patrice, Donfack
    Materny, Arnulf
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2018, 347 : 266 - 278