In this paper, we construct a family of new solutions for the following nonlinear Schr & ouml;dinger system:{ Delta-u + P(y)u = mu u3 +beta uv2, u > 0, in R-3,-Delta v+ Q(y)v= nu v3 + beta u2v, v> 0, in R3,where P(y), Q(y) are positive radial potentials, mu > 0, nu > 0 and beta is an element of R. Motivated by the doubling construction of the entire finite energy sign-changing solution for the Yamabe equation in M. Medina and M. Musso (J. Math. Pures Appl. 2021), by using another type of building blocks, which are not equal to the ones adopted in S. Peng and Z.-Q. Wang (Arch. Ration. Mech. Anal. 2013), we successfully construct new segregated and synchronized vector solutions for the nonlinear Schr & ouml;dinger system with more complex concentration structure. Our results extend the main results of S. Peng and Z.-Q. Wang (Arch. Ration. Mech. Anal. 2013), and in particular, for the segregated case, we well complement the previous works when the potentials P(y) and Q(y) decay in different rates.