Phase Behavior of Isobutane + CO2 and Isobutane + H2 at Temperatures Between 190 and 400 K and at Pressures Up to 20 MPa

Mixtures containing isobutane, carbon dioxide, and/or hydrogen are found in various industrial processes, green refrigerant systems, and the growing hydrogen industry. Understanding the thermophysical properties of these mixtures is essential for these processes, and depends on reliable experimental data. Making use of an automated static-analytical apparatus, measurements were made of the phase behavior of binary mixtures of isobutane with CO2 and with H-2, extending the range of available data for both mixtures. Measurements of the system isobutane + CO2 were carried out along three isotherms at temperatures of (240, 280, and 310) K with pressures from the lower limit of the sampling system (similar to 0.5 MPa) to the mixture critical pressure. The results exhibit good agreement with literature data. Measurements on isobutane + H-2 were carried out along nine isotherms at temperatures of (190, 240, 280, 311, 339, 363, 375, 390, and 400) K with pressures up to 20 MPa, covering a much broader range of conditions than the one prior investigation. The results have been used to optimize temperature-dependent binary parameters in the Peng-Robinson equation of state with two different mixing rules. This approach was found to perform well in comparison to alternative models.