Thermal Conductivity of Covalent-Organic Frameworks

被引：25

作者：

Kwon, Jinha ^{[1
]}

Ma, Hao ^{[2
,3
]}

Giri, Ashutosh ^{[4
]}

Hopkins, Patrick E. ^{[5
,6
,7
]}

Shustova, Natalia B. ^{[8
]}

Tian, Zhiting ^{[1
]}

机构：

[1] Cornell Univ, Sibley Sch Mech & Aerosp Engn, Ithaca, NY 14853 USA

[2] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA

[3] Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China

[4] Univ Rhode Isl, Mech Ind & Syst Engn, Kingston, RI 02881 USA

[5] Univ Virginia, Dept Mech & Aerosp Engn, Charlottesville, VA 22904 USA

[6] Univ Virginia, Dept Mat Sci & Engn, Charlottesville, VA 22904 USA

[7] Univ Virginia, Dept Phys, Charlottesville, VA 22904 USA

[8] Univ South Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

ACS NANO | 2023年 / 17卷 / 16期

关键词：

covalent-organic frameworks; thermal conductivity; thermal management; COFS; CRYSTALLINE; LEAD;

D O I：

10.1021/acsnano.3c03518

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent-organic frameworks (COFs)are a highly promisingclassof materials that can provide an excellent platform for thermal managementapplications. In this Perspective, we first review previous workson the thermal conductivities of COFs. Then we share our insightson achieving high, low, and switchable thermal conductivities of futureCOFs. To obtain the desired thermal conductivity, a comprehensiveunderstanding of their thermal transport mechanisms is necessary butlacking. We discuss current limitations in atomistic simulations,synthesis, and thermal conductivity measurements of COFs and sharepotential pathways to overcoming these challenges. We hope to stimulatecollective, interdisciplinary efforts to study the thermal conductivityof COFs and enable their wide range of thermal applications.

引用

页码：15222 / 15230

页数：9

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