Recent Progress in Surface-Defect Engineering Strategies for Electrocatalysts toward Electrochemical CO2 Reduction: A Review

Climate change, caused by greenhouse gas emissions, is one of the biggest threats to the world. As per the IEA report of 2021, global CO2 emissions amounted to around 31.5 Gt, which increased the atmospheric concentration of CO2 up to 412.5 ppm. Thus, there is an imperative demand for the development of new technologies to convert CO2 into value-added feedstock products such as alcohols, hydrocarbons, carbon monoxide, chemicals, and clean fuels. The intrinsic properties of the catalytic materials are the main factors influencing the efficiency of electrochemical CO2 reduction (CO2-RR) reactions. Additionally, the electroreduction of CO2 is mainly affected by poor selectivity and large overpotential requirements. However, these issues can be overcome by modifying heterogeneous electrocatalysts to control their morphology, size, crystal facets, grain boundaries, and surface defects/vacancies. This article reviews the recent progress in electrochemical CO2 reduction reactions accomplished by surface-defective electrocatalysts and identifies significant research gaps for designing highly efficient electrocatalytic materials.