Hybrid macrocyclic polyoxoanions based on {Mo3S4}4+ and γ-[SiW10O36]8- as inorganic ligands

被引：2

作者：

Korenev, V. S. ^{[1
]}

Sukhikh, T. S. ^{[1
]}

Sokolov, M. N. ^{[1
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Prosp Acad Lavrentieva, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 01期

关键词：

polyoxometalates; chalcogenide clusters; cubane clusters; building blocks; supramolecular chemistry; CUBOIDAL CLUSTERS; CRYSTAL-STRUCTURE; BUILDING-BLOCK; POLYOXOMETALATE; MO; COMPLEXES; CATALYSIS; UNITS; MO3S4; SB;

D O I：

10.1007/s11172-023-3720-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polyoxoanion [{Mo3S4(H2O)(4)(tu)}(2){Mo3S4(H2O)(3)(tu)(2)}(2)(gamma-SiW10O36)(4)](16-) was obtained by the reaction of lacunary silicotungstate [gamma-SiW10O36](8-) with the trinuclear cluster cation Mo3S4(tu)(8)(H2O)](4+) (tu is thiourea, (NH2)(2)CS)). Its reaction with copper(I) iodide in the presence of chloride anions affords tetracubane polyoxometalate [{Mo3S4Cu(H2O)(5)}(4)Cl(gamma-SiW(10)O(3)6)(4)](13-), and the reaction with silver acetate gives the previously described [{Mo3S4(H2O)(5)}(4)(gamma-SiW10O36)(4)](16-). The compounds were isolated as potassium sodium salts and structurally characterized.

引用

页码：158 / 166

页数：9

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