Low-carbon magnesium potassium phosphate cement (MKPC) binder comprising caustic calcined magnesia and potassium hydroxide activated biochar from softwood technical lignin

被引:8
作者
Opara, Emmanuel Uchechukwu [1 ]
Karthauser, Johannes [1 ]
Kohler, Robert [2 ,4 ]
Kowald, Torsten [3 ]
Koddenberg, Tim [1 ]
Mai, Carsten [1 ]
机构
[1] Georg August Univ Goettingen, Dept Wood Biol & Wood Prod, Busgenweg 4, D-37077 Gottingen, Germany
[2] Univ Appl Sci & Arts, Fac Engn & Hlth, Von Ossietzky Str 99, D-37085 Gottingen, Germany
[3] Univ Siegen, Dept Chem & Biol, Chem & Struct Novel Mat, Paul Bonatz Str 9-11, D-57076 Siegen, Germany
[4] Fraunhofer Inst Surface Engn & Thin Films IST, Applicat Ctr Plasma & Photon, Von Ossietzky Str 100, D-37085 Gottingen, Germany
关键词
Sustainable Construction; Magnesium Potassium Phosphate Cement; Caustic Calcined Magnesia; Low-carbon cement; Biochar Augmented Cement; FLY-ASH; WOOD; XPS; PYROLYSIS; CERAMICS; SORBENT; PASTE; OXIDE; KOH;
D O I
10.1016/j.conbuildmat.2023.132475
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Biochar augmentation in cementitious materials is attractive for enhancing the products' mechanical properties and improving sustainability. Softwood technical lignin biochar (5 wt-%) was used to augment MKPC as a replacement material, with increased surface area through KOH activation. Hard-burned (1000 degrees C) MgO was used as precursor. XRD and SEM-EDX analyses showed "struvite-K" as the primary component of the MKPC materials. MKPC materials including the 2-hour KOH-activated biochar showed the lowest porosity, highest strength and stiffness. Replacing MKPC with KOH-activated biochar can increase strength properties and reduce MKPC binder usage, providing a sustainable approach for precast applications.
引用
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页数:13
相关论文
共 64 条
[1]   Microstructural characterization of basalt fiber reinforced magnesium phosphate cement supplemented by silica fume [J].
Ahmad, Muhammad Riaz ;
Chen, Bing .
CONSTRUCTION AND BUILDING MATERIALS, 2020, 237
[2]   A comprehensive study of basalt fiber reinforced magnesium phosphate cement incorporating ultrafine fly ash [J].
Ahmad, Muhammad Riaz ;
Chen, Bing ;
Yu, Jiang .
COMPOSITES PART B-ENGINEERING, 2019, 168 :204-217
[3]   Magnesium based phosphate cement binder for composite panels: A response surface methodology for optimisation of processing variables in boards produced from agricultural and wood processing industrial residues [J].
Amiandamhen, S. O. ;
Meincken, M. ;
Tyhoda, L. .
INDUSTRIAL CROPS AND PRODUCTS, 2016, 94 :746-754
[4]  
[Anonymous], 2013, BEST AVAILABLE TECHN
[5]  
[Anonymous], 2016, 1961201611 DIN EN BE
[6]   Insight into KOH activation mechanism during biomass pyrolysis: Chemical reactions between O-containing groups and KOH [J].
Chen, Wei ;
Gong, Meng ;
Li, Kaixu ;
Xia, Mingwei ;
Chen, Zhiqun ;
Xiao, Haoyu ;
Fang, Yang ;
Chen, Yingquan ;
Yang, Haiping ;
Chen, Hanping .
APPLIED ENERGY, 2020, 278
[7]   Study of chemical activation process of a lignocellulosic material with KOH by XPS and XRD [J].
Díaz-Terán, J ;
Nevskaia, DM ;
Fierro, JLG ;
López-Peinado, AJ ;
Jerez, A .
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 60 (1-3) :173-181
[8]   Effect of aggregates and water contents on the properties of magnesium phospho-silicate cement [J].
Ding, Z ;
Li, ZJ .
CEMENT & CONCRETE COMPOSITES, 2005, 27 (01) :11-18
[9]   Study on an Improved Phosphate Cement Binder for the Development of Fiber-Reinforced Inorganic Polymer Composites [J].
Ding, Zhu ;
Dai, Jian-Guo ;
Muner, Sarfraz .
POLYMERS, 2014, 6 (11) :2819-2831
[10]   Waste Valorisation using biochar for cement replacement and internal curing in ultra-high performance concrete [J].
Dixit, Anjaneya ;
Gupta, Souradeep ;
Pang, Sze Dai ;
Kua, Harn Wei .
JOURNAL OF CLEANER PRODUCTION, 2019, 238