Mechanical property enhancement of sintered Nd-Fe-B magnets by dual-scale regulation of microstructure

被引:10
作者
Zhong, Shuwei [1 ,2 ]
Yang, Munan [1 ,2 ,3 ,4 ]
Rehman, Sajjad Ur [2 ,4 ]
Luo, Sangen [1 ,2 ]
Li, Longgui [5 ]
Li, Chao [5 ]
Li, Jiajie [1 ]
Ma, Qiang [3 ]
Xiong, Shuhua [4 ,6 ]
Bulyk, Ihor [1 ]
Yang, Bin [1 ]
机构
[1] Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Ganzhou 341000, Peoples R China
[2] Jiangxi Univ Sci & Technol, Key Lab Dev & Applicat Ion Rare Earth Resources, Minist Educ, Ganzhou 341000, Peoples R China
[3] Ganjiang Innovat Acad, Chinese Acad Sci, Ganzhou 341000, Peoples R China
[4] Natl Rare Earth Funct Mat Innovat Ctr, Ganzhou 341000, Peoples R China
[5] Ganzhou Dongci Rare Earth Co Ltd DMEGC, Ganzhou 341000, Peoples R China
[6] Jiangxi Rare Earth Funct Mat Technol Co Ltd, Ganzhou 341000, Peoples R China
关键词
Sintered Nd-Fe-B magnets; Rod-like Ti particles; Mechanical properties; Amorphous phase; Dual-scale regulation; IMPACT TOUGHNESS; RICH PHASE; COERCIVITY; CO; TI; DEPENDENCE;
D O I
10.1016/j.intermet.2022.107772
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The brittleness of sintered Nd-Fe-B magnet limits its applications in high frequency and high vibration envi-ronments. In this study, rod-like Ti particles were applied for dual-scale microstructure regulation to improve the mechanical properties of sintered Nd-Fe-B magnets. The bending strength of Ti-added magnets increased from 403.47 to 631.98 MPa, which shows an increase of 56.6%. The intrinsic coercivity of the Ti-added magnet increased from 15.20 kOe to 17.52 kOe. The mechanical properties and intrinsic coercivity are significantly improved without reducing the remanence. The Ti particles reduced the grain size and favorably altered the alignment of the grains, and hence effectively reduced the stress concentration effect. Furthermore, Ti particles promoted the formation of nano amorphous phase in the grain boundary phase, which greatly improved the strength of the grain boundary phase. This study provides a theoretical basis for the preparation of sintered Nd-Fe-B magnets with excellent mechanical properties.
引用
收藏
页数:9
相关论文
共 39 条
[11]   Effect of Tb on the intrinsic coercivity and impact toughness of sintered Nd-Dy-Fe-B magnets [J].
Hu, Z. H. ;
Lian, F. Z. ;
Zhu, M. G. ;
Li, W. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (11) :1735-1738
[12]   Effects of Nb on the coercivity and impact toughness of sintered Nd-Fe-B magnets [J].
Hu, Z. H. ;
Zhu, M. G. ;
Li, W. ;
Lian, F. Z. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (3-4) :96-99
[13]   Microstructure evolution and coercivity enhancement in Pr50Dy20Cu15Ga15-doped hot-deformed Nd-Fe-B magnets [J].
Huang, Xiangyun ;
Li, Jiajie ;
Rehman, Sajjad Ur ;
Quas, Pengpeng ;
He, Lei ;
Zeng, Liangliang ;
Yu, Xiaoqiang ;
Yang, Munan ;
Zhong, Zhenchen .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2020, 503
[14]   Influence of alloying elements on mechanical properties and microstructures of sintered Nd-Fe-Co-B magnet [J].
Jiang, JH ;
Zeng, ZP ;
Wu, JS ;
Tokunaga, M .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2000, 214 (1-2) :61-68
[15]   The effect of Co addition on the fracture strength of NdFeB sintered magnets [J].
Jiang, JH ;
Zeng, ZP ;
Yu, J ;
Wu, JS ;
Tokunaga, M .
INTERMETALLICS, 2001, 9 (04) :269-272
[16]   Simultaneous application of Dy-X (X = F or H) powder doping and dip-coating processes to Nd-Fe-B sintered magnets [J].
Kim, Tae-Hoon ;
Lee, Seong-Rae ;
Kim, Hyo-Jun ;
Lee, Min-Woo ;
Jang, Tae-Suk .
ACTA MATERIALIA, 2015, 93 :95-104
[17]   A study on the Nd-rich phase evolution in the Nd-Fe-B sintered magnet and its mechanism during post-sintering annealing [J].
Kim, Tae-Hoon ;
Lee, Seong-Rae ;
Namkumg, Seok ;
Jang, Tae-Suk .
JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 537 :261-268
[18]   ANALYTICAL ELECTRON-MICROSCOPY OF TI-DOPED ND-TM-B MAGNETS [J].
KITANO, Y ;
SHIMOMURA, J ;
SHIMOTOMAI, M .
JOURNAL OF APPLIED PHYSICS, 1991, 69 (08) :6055-6057
[19]   The origin of coercivity enhancement in newly prepared high coercivity Dy-free Nd-Fe-B sintered magnets [J].
Kobayashi, Kurima ;
Urushibata, Kimiko ;
Une, Yasuhiro ;
Sagawa, Masato .
JOURNAL OF APPLIED PHYSICS, 2013, 113 (16)
[20]   Amorphous-nanocrystalline alloys: fabrication, properties, and applications [J].
Li, F. C. ;
Liu, T. ;
Zhang, J. Y. ;
Shuang, S. ;
Wang, Q. ;
Wang, A. D. ;
Wang, J. G. ;
Yang, Y. .
MATERIALS TODAY ADVANCES, 2019, 4