In-situ photoreduction strategy for synthesis of silver nanoparticle-loaded PVDF ultrafiltration membrane with high antibacterial performance and stability

Ultrafiltration (UF) technology using polyvinylidene fluoride (PVDF) membrane has been widely applied to water and wastewater treatment due to its low cost and simple operation process. However, PVDF-based UF membrane always encountered the issue of membrane biofouling that greatly impacted the filtration performance. In this study, we prepare a silver nanoparticle (AgNP)-loaded PVDF (Ag/PVDF) UF membrane by an in-situ photoreduction method to mitigate the membrane biofouling. Different from the previously reported method, AgNPs were synthesized in-situ by a UV photoreduction process, in which Ag+ ions were reduced to zero-valent Ag nanoparticles by the photo-induced reducing radicals. Antibacterial experiments showed that the inhibition efficiency of Ag/PVDF membrane to Escherichia coli reached up to similar to 99% after antibacterial treatment for 24 h. In comparison with the pristine PVDF membrane, Ag/PVDF membrane possessed a lower water contact angle (83.7 degrees vs. 38.1 degrees), and its pure water flux increased by 23.7%, and a high bovine serum albumin (BSA) rejection efficiency was maintained. In addition, the high stability of the Ag/PVDF composite membrane was confirmed by the extremely low releasing amount of Ag. This study provides a novel strategy for the preparation of metal nanoparticle-incorporated Ag/PVDF ultrafiltration composite membrane showing favorable antibacterial performance and stability.