Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide: The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101

被引：8

作者：

Obeso, Juan L. ^{[1
,2
]}

Flores, J. Gabriel ^{[3
,4
]}

Flores, Catalina V. ^{[1
,2
]}

Rios-Escobedo, Reyna ^{[3
]}

Aguilar-Pliego, Julia ^{[4
]}

Inge, A. Ken ^{[5
]}

de los Reyes, Jose Antonio ^{[3
]}

Peralta, Ricardo A. ^{[6
]}

Ibarra, Ilich A. ^{[2
]}

Leyva, Carolina ^{[1
]}

机构：

[1] Inst Politecn Nacl, CICATA, Legaria, Miguel Hidalgo 11500, Mexico

[2] Univ Nacl Autonoma Mexico, Lab Fisicoquim & React Superf LaFReS, Inst Invest Mat, Coyoacan, Ciudad De Mexico 04510, Mexico

[3] Univ Autonoma Metropolitana Iztapalapa, Dept Ingn Proc & Hidraul, Div Ciencias Bas Ingn, Ciudad De Mexico 09340, Mexico

[4] Univ Autonoma Metropolitana Azcapotzalco, Dept Quim Aplicada, Azcapotzalco, Ciudad De Mexico 02200, Mexico

[5] Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden

[6] Univ Autonoma Metropolitana UAM I, Dept Quim, Div Ciencias Bas Ingn, Ciudad De Mexico 09340, Mexico

来源：

CHEMCATCHEM | 2023年 / 15卷 / 13期

关键词：

alcoholysis; heterogeneous catalysis; Lewis acids; metal-organic frameworks; open-metal sites; HETEROGENEOUS CATALYSTS; EFFICIENT; EPOXIDES; CO2; CYCLOADDITION; SOLVENT;

D O I：

10.1002/cctc.202300471

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

SU-101 was screened for the acid-catalyzed ring-opening alcoholysis of cyclohexene oxide. Results indicated access to open metal sites within SU-101, a fundamental requirement (Lewis acid Bi+3 sites) for this reaction. In addition, SU-101 exhibited high chemical stability, demonstrated by retaining its crystalline structure after the reaction. The cyclohexene conversion was estimated to be 99.8, 96.8, and 14.3 % at 40 degrees C for methanol, ethanol, and propanol, respectively. Also, SU-101 demonstrated an outstanding catalytic cyclability performance for five cycles without losing catalytic activity.

引用

页数：5

共 15 条

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Obeso, Juan L.
Flores, J. Gabriel
Flores, Catalina V.
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Martinez-Jimenez, V.
de los Reyes, Jose Antonio
Lima, Enrique
Solis-Ibarra, Diego
Ibarra, Ilich A.
Leyva, Carolina
Peralta, Ricardo A.
DALTON TRANSACTIONS, 2023, 52 (35) : 12490 - 12495
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Tanaka, Koichi
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Nishihote, Shyota
Urbanczyk-Lipkowska, Zofia
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2012, 85 (06) : 709 - 714
[3] Enantioselective ring-opening reaction of epoxides with MeOH catalyzed by homochiral metal-organic framework
Tanaka, Koichi
Otani, Ken-Ichi
Murase, Takanori
Nishihote, Shyota
Urbanczyk-Lipkowska, Zofia
Bulletin of the Chemical Society of Japan, 2012, 85 (06): : 709 - 714
[4] Copper-based metal-organic framework for the facile ring-opening of epoxides
Jiang, Dongmei
Mallat, Tarnas
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JOURNAL OF CATALYSIS, 2008, 257 (02) : 390 - 395
[5] Ring-opening copolymerization of ε-caprolactone and δ-valerolactone by a titanium-based metal-organic framework
Abdur, Rahaman M.
Mousavi, Bibimaryam
Shahadat, Hossain M.
Akther, Nishat
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Zhuiykov, Serge
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NEW JOURNAL OF CHEMISTRY, 2021, 45 (25) : 11313 - 11316
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CHEMICAL COMMUNICATIONS, 2013, 49 (84) : 9836 - 9838
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Yang, Qi
Wang, Bin
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CHINESE CHEMICAL LETTERS, 2019, 30 (01) : 234 - 238
[8] Air-stable titanium alkoxide based metal-organic framework as an initiator for ring-opening polymerization of cyclic esters
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INORGANIC CHEMISTRY, 2006, 45 (17) : 6595 - 6597
[9] Research Update: A hafnium-based metal-organic framework as a catalyst for regioselective ring-opening of epoxides with a mild hydride source
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APL MATERIALS, 2014, 2 (12):
[10] The mechanism of an asymmetric ring-opening reaction of epoxide with amine catalyzed by a metal-organic framework: insights from combined quantum mechanics and molecular mechanics calculations
Doitomi, Kazuki
Xu, Kai
Hirao, Hajime
DALTON TRANSACTIONS, 2017, 46 (11) : 3470 - 3481

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