Surface response modeling of homogeneous photo Fenton Fe(III) and Fe(II) complex for sunlight degradation and mineralization of food dye

被引:18
作者
Kebir, Mohammed [1 ]
Benramdhan, Imen-Kahina [2 ]
Nasrallah, Noureddine [2 ]
Tahraoui, Hichem [3 ,4 ]
Bait, Nadia [1 ]
Benaissa, Houssine [5 ]
Ameraoui, Rachid [6 ]
Zhang, Jie [7 ]
Assadi, Aymen Amin [8 ,9 ]
Mouni, Lotfi [10 ]
Amrane, Abdeltif [8 ]
机构
[1] Res Unit Phys & Chem Anal Fluid & Solid Media UR A, BP 384 Bou Ismail, Tipasa 42000, Algeria
[2] Fac Mech Engn & Proc Engn USTHB, Lab React Engn, BP 32, Algiers 16111, Algeria
[3] Univ Ferhat Abbas, Dept Proc Engn, Lab Genie Proc Chim, Setif, Algeria
[4] Univ Yahia Fares Medea Pole Urbain, Lab Biomat & Phenomenes Transports LBMPT, Medea 26000, Algeria
[5] Ecole Mil Polytech, LEC, BEB, BP17, Algiers 16111, Algeria
[6] Ctr Rech Sci & Tech Anal Physicochim CRAPC, BP 384, Bou Ismail 42004, Tipaza, Algeria
[7] Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, England
[8] Univ Rennes, Ecole Natl Super Chim Rennes, CNRS, ISCR,UMR 6226, F-35000 Rennes, France
[9] Al Imam Mohammad Ibn Saud Islamic Univ IMISIU, Dept Chem, POB 5701, Riyadh 11432, Saudi Arabia
[10] Univ Bouira, SNVST Fac, Lab Management & Valorizat Nat Resources & Qual As, Bouira 10000, Algeria
关键词
Complex; Degradation; Food dye; Mineralization; Box-Benhken design; Response surface; WASTE-WATER; OPTIMIZATION; CHLORIDE; OXIDATION; SULFATE; IONS; REMOVAL; PHENOL;
D O I
10.1016/j.catcom.2023.106780
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study explores efficient Sicomet Green (SG) dye degradation using Fe(III)/Lig and Fe(II)/Lig complexes in modified photo-Fenton processes under UV, LED, and sunlight. Sunlight irradiation showed rapid kinetics with over 70% degradation efficiency. Multi-objective grey wolf optimization achieved 98% degradation and 96% mineralization yield using Fe(III)/Lig without pH adjustment. Inorganic ions inhibited the modified photoFenton process. A user-friendly app aided predictions and optimal parameters selection, emphasizing natural light sources and pH-neutral medium for dye removal through photo-Fenton.
引用
收藏
页数:16
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