Visible Light-Driven, Persulfate-Mediated Hydrocarboxylation of Vinylsulfones

被引：2
作者：
Palvoelgyi, Adam Mark [1 ]
Scharinger, Fabian [1 ]
Bauhoff, Thomas [1 ]
Bica-Schroeder, Katharina [1 ]
机构：
[1] TU Wien, Inst Appl Synthet Chem, Getreidemarkt 9-163, A-1060 Vienna, Austria
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2023年 / 365卷 / 18期
基金：
欧洲研究理事会;
关键词：
Hydrocarboxylation; CO2 radical anion; Potassium persulfate; Visible light; Hydrogen atom transfer; BETA-SELECTIVE HYDROCARBOXYLATION; C-H; CATALYZED HYDROCARBOXYLATION; CO2; STYRENES; FORMATE; HYDROXYCARBONYLATION; PHOTOCATALYSIS; ACTIVATION; COMPLEXES;
D O I：
10.1002/adsc.202300654
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
We report a visible light-mediated approach for the radical hydrocarboxylation of vinylsulfone derivatives. Using cheap and easily accessible sodium formate as C1-source and K2S2O8 as reagent, a set of vinylsulfone substrates could be efficiently hydrocarboxylated in aqueous medium without any additional catalyst or reagent; and the concept could be also applied for direct hydroacylations, hydroalkylations and hydrophosphorylations. The control experiments clearly indicated that the reaction proceeds via radical mechanism without the generation of electron donor-acceptor (EDA) complexes; supporting the working model of K2S2O8-initiated in situ formation of CO2 radical anion.
引用
收藏
页码：3069 / 3074
页数：6
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