Copillar[5]arene Chemistry: Synthesis and Applications

被引：2

作者：

Chen, Wenzhang ^{[1
,2
]}

Vincent, Stephane P. ^{[2
]}

机构：

[1] Guizhou Med Univ, Guizhou Prov Engn Technol Res Ctr Chem Drug R&D, Guiyang 550004, Peoples R China

[2] UNamur, NARILIS, Dept Chem, Rue Bruxelles 61, B-5000 Namur, Belgium

来源：

SYNTHESIS-STUTTGART | 2023年 / 55卷 / 02期

关键词：

copillararenes; supramolecular chemistry; macrocycles; host-guest compounds; phenols; AGGREGATION-INDUCED EMISSION; HOST-GUEST COMPLEXATION; ONE-POT SYNTHESIS; DIASTEREOSELECTIVE SYNTHESIS; MULTIVALENT BINDING; WATER; RECOGNITION; GLYCOCLUSTERS; DERIVATIVES; INHIBITION;

D O I：

10.1055/s-0040-1738369

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Research on pillar[n]arenes has witnessed a very quick expansion. This emerging class of functionalized macrocyclic oligoarenes not only offers host-guest properties due to the presence of the central cavity, but also presents a wide variety of covalent functionalization possibilities. This short review focuses on copillararenes, a subfamily of pillar[n]arenes. In copillararenes, at least one of the hydroquinone units bears different functional groups compared to the others. After having defined the particular features of copillararenes, this short review compares the different synthetic strategies allowing their construction. Some key applications and future perspectives are also described. 1 Introduction 2 General Features of Pillar[5]arenes 3 Synthesis of Functionalized Copillar[4+1]arenes 4 Concluding Remarks

引用

页码：246 / 262

页数：17

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