Processing and Properties of Garnet-Type Li7La3Zr2O12 Ceramic Electrolytes

被引：48
作者：
Chen, Chao [1 ,2 ]
Wang, Kexin [1 ,2 ]
He, Hongying [3 ]
Hanc, Emil [4 ]
Kotobuki, Masashi [5 ]
Lu, Li [1 ,2 ]
机构：
[1] Natl Univ Singapore, Chongqing Res Inst, Chongqing 401123, Peoples R China
[2] Natl Univ Singapore, Dept Mech Engn, 21 Lower Kent Ridge Rd, Singapore 117575, Singapore
[3] Nanyang Technol Univ, Sch Mech & Aerosp Engn, Singapore 639798, Singapore
[4] Polish Acad Sci, Mineral & Energy Econ Res Inst, PL-31261 Krakow, Poland
[5] Ming Chi Univ Technol, Battery Res Ctr Green Energy, 84 Gungjuan Rd, New Taipei 243, Taiwan
来源：
SMALL | 2023年 / 19卷 / 12期
关键词：
calcination; Garnet-type Li7La3Zr2O12; processing; sintering; solid state batteries; AL-DOPED LI7LA3ZR2O12; LI-ION CONDUCTIVITY; LOW-TEMPERATURE SYNTHESIS; SOLID-STATE BATTERY; CUBIC LI7LA3ZR2O12; ELECTROCHEMICAL PROPERTIES; INTERFACIAL RESISTANCE; LITHIUM GARNETS; SUBSTITUTED LI7LA3ZR2O12; SINTERING ADDITIVES;
D O I：
10.1002/smll.202205550
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Garnet-type solid electrolyte Li7La3Zr2O12 (LLZO) is widely considered as one of the most promising candidates for solid state batteries (SSBs) owing to its high ionic conductivity and good electrochemical stability. Since its discovery in 2007, great progress has been made in terms of crystal chemistry, chemical and electrochemical properties, and battery application. Nonetheless, reliable and controllable preparation of LLZO ceramics with desirable properties still remains as big challenges. Herein, this review summarizes various synthetic routes of LLZO ceramics and examines the influence of various key processing parameters on the chemical and electrochemical properties. Focusing on correlation of processing parameters and properties, this review aims to provide new insights on a reliable and controllable production of high-quality LLZO ceramic electrolytes for SSB application.
引用
收藏
页数：33
相关论文
共 50 条
  • [21] Challenges to Li7La3Zr2O12 system electrolyte and the modification: From powder to ceramic
    Xiao, Yiyang
    Yang, Juanyu
    Wang, Ning
    Zhang, Xiaobao
    Liang, Shiang
    Zhao, Huan
    Du, Lei
    Chen, Jun
    Huang, Xiaowei
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 986
  • [22] Composite electrolytes ceramic Li7La3Zr2O12/glassy Li2O-Y2O3-SiO2
    Il'ina, E. A.
    Raskovalov, A. A.
    Antonov, B. D.
    Pankratov, A. A.
    Reznitskikh, O. G.
    [J]. MATERIALS RESEARCH BULLETIN, 2017, 93 : 157 - 161
  • [23] Efficient Anion Fluoride-Doping Strategy to Enhance the Performance in Garnet-Type Solid Electrolyte Li7La3Zr2O12
    Ma, Xiaoning
    Xu, Youlong
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (02) : 2939 - 2948
  • [24] Low temperature synthesis of Ga-doped Li7La3Zr2O12 garnet-type solid electrolyte by mechanical method
    Kanai, Kazuaki
    Ozawa, Shinji
    Kozawa, Takahiro
    Naito, Makio
    [J]. ADVANCED POWDER TECHNOLOGY, 2021, 32 (10) : 3860 - 3868
  • [25] Microstructural and Electrochemical Properties of Al- and Ga-Doped Li7La3Zr2O12 Garnet Solid Electrolytes
    Chen, Chao
    Sun, Yao
    He, Linchun
    Kotobuki, Masashi
    Hanc, Emil
    Chen, Yu
    Zeng, Kaiyang
    Lu, Li
    [J]. ACS APPLIED ENERGY MATERIALS, 2020, 3 (05) : 4708 - 4719
  • [26] Dynamic lithium-compensation mechanism for densification of garnet-type Li7La3Zr2O12 electrolyte by Li2O atmosphere buffer pair
    Zheng, Chujun
    Chen, Ya
    Dong, Haoxin
    Lu, Yan
    Jin, Jun
    Wen, Zhaoyin
    [J]. NANO RESEARCH, 2024, 17 (07) : 6184 - 6191
  • [27] High Li ion conductivity in strontium doped Li7La3Zr2O12 garnet
    Dumon, Alexandre
    Huang, Mian
    Shen, Yang
    Nan, Ce-Wen
    [J]. SOLID STATE IONICS, 2013, 243 : 36 - 41
  • [28] Li-In alloy: preparation, properties, wettability of solid electrolytes based on Li7La3Zr2O12
    Il'ina, E. A.
    Druzhinin, K., V
    Lyalin, E. D.
    Plekhanov, M. S.
    Talankin, I. I.
    Antonov, B. D.
    Pankratov, A. A.
    [J]. JOURNAL OF MATERIALS SCIENCE, 2022, 57 (02) : 1291 - 1301
  • [29] Thermodynamic properties of solid electrolyte Li7La3Zr2O12
    Il'ina, E. A.
    Raskovalov, A. A.
    Reznitskikh, O. G.
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2019, 128 : 68 - 73
  • [30] Experimental and Computational Study of Mg and Ta-Doped Li7La3Zr2O12 Garnet-Type Solid Electrolytes for All-Solid-State Lithium Batteries
    Ma, Kai
    Chen, Bowen
    Li, Cheng-Xin
    Thangadurai, Venkataraman
    [J]. ADVANCED SUSTAINABLE SYSTEMS, 2024, 8 (06)
12345