Catalytic Atroposelective Synthesis of Axially Chiral Heterobiaryl Oxime Ethers via the One-Step Dynamic Kinetic Condensation Reaction

被引：7

作者：

Xu, Qianqian ^{[1
]}

Jia, Jifan ^{[1
]}

Fan, Haitong ^{[1
]}

Ma, Zhifeng ^{[2
]}

Wu, Yuqing ^{[1
]}

Zhang, Yifeng ^{[3
]}

Su, Ping ^{[3
]}

Gao, Wei ^{[1
]}

Wang, Yuji ^{[1
]}

Li, Dan ^{[1
]}

机构：

[1] Capital Med Univ, Sch Pharmaceut Sci, Beijing 100069, Peoples R China

[2] Yunnan Minzu Univ, Sch Chem & Environm, Kunming 650500, Yunnan, Peoples R China

[3] China Acad Chinese Med Sci, Natl Resource Ctr Chinese Mat Med, State Key Lab Qual Ensurance & Sustainable Use Dao, Beijing 100700, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 12期

基金：

国家重点研发计划;

关键词：

ASYMMETRIC CONSTRUCTION; DESYMMETRIZATION; RESOLUTION; ATROPISOMERISM;

D O I：

10.1021/acs.orglett.4c00479

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic atroposelective synthesis of axially chiral heterobiaryls was first developed through the direct one-step dynamic kinetic condensation reaction with the simple transformation of the C= O bond to the C= N bond, delivering a series of novel axially chiral heterobiaryl oxime ethers.

引用

页码：2403 / 2408

页数：6

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