Crystal Structure of Inclusion Compounds Based on Porous Trans-Thienothiophendicarboxylate of Europium(III) with Norbornadiene and Trans-Cinnamyl Alcohol

被引：1
作者：
Demakov, P. A. [1 ]
Lazarenko, V. A. [2 ]
Dorovatovskii, P. V. [2 ]
Fedin, V. P. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Kurchatov Inst, Natl Res Ctr, Moscow, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2023年 / 64卷 / 12期
基金：
俄罗斯科学基金会;
关键词：
metal organic frameworks; single crystal X-ray diffraction analysis; inclusion compounds; norbornadiene; cinnamyl alcohol; METAL-ORGANIC-FRAMEWORKS; LUMINESCENT PROPERTIES; COMPLEXES; DIARYLCYCLOBUTANES; POLYMERIZATION; LIGANDS; MOFS;
D O I：
10.1134/S0022476623120132
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A europium(III) coordination compound based on thiopheneacrylic acid (Htpa), triaquatris[3-(thiophen-2-yl)prop-2-enoato-kappa(2) O,O ']europium(III)-3-(thiophen-2-yl)prop-2-enoic acid (1/3), [Eu(C7H5O2S)(3)(H2O)(3)]<middle dot>3C(7)H(6)O(2)S or [Eu(tpa)(3)(H2O)(3)]<middle dot>3(Htpa) (<bold>1</bold>), where tpa is the conjugate base of Htpa, has been synthesized and structurally characterized. Compound <bold>1</bold> crystallizes in the trigonal space group R3. The structure of <bold>1</bold> consists of a discrete molecular complex [Eu(tpa)(3)(H2O)(3)] species and the Htpa molecule. In the crystal, the two components are involved in O-H & ctdot;O [ring motif R (2) (2)(8)] and C-H & ctdot;pi hydrogen-bonding interactions. These interactions were further investigated by Hirshfeld surface analysis, which showed high contributions of H & ctdot;H, H & ctdot;C/C & ctdot;H and H & ctdot;O/O & ctdot;H contacts to the total Hirshfeld surfaces.
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页码：2417 / 2426
页数：10
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