[4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Amidophenolato][4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Iminobenzosemiquinolato](2,2′-Bipyridyl)Indium(III)

被引：0

作者：

Ershova, Irina V. V. ^{[1
]}

Cherkasov, Anton V. V. ^{[1
]}

Piskunov, Alexandr V. V. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, 49 Tropinina Str, Nizhnii Novgorod 603950, Russia

来源：

MOLBANK | 2023年 / 2023卷 / 02期

关键词：

indium; redox-active ligand; o-amidophenolate; o-iminobenzosemiquinolate; bipyridyl; charge transfer; ESR; X-ray diffraction; CHARGE-TRANSFER; CATECHOLATE LIGANDS; METAL-COMPLEXES; DIIMINE; DONOR; NICKEL; STATES; DYES;

D O I：

10.3390/M1660

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A six-coordinated indium(III) complex (AP(Me))(imSQ(Me))In(bipy) (1), bearing two types of redox-active ligands-mono- (imSQ(Me)) and dianion (AP(Me)) of 4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-o-iminobenzoquinone and 2,2 & PRIME;-bipyridyl-was synthesized and characterized in detail. The intense, well-resolved ESR spectrum of 1 in dichloromethane solution clearly indicates the spin density delocalization between both AP and imSQ ligands. The UV-vis spectrum of 1 possesses an absorption band in the NIR region. The molecular structure of compound 1 was established by single-crystal X-ray diffraction analysis.

引用

页数：7

共 50 条

[31] 2,6-Di-tert-butyl-4-(hydroxymethyl) phenol
Bai, Guo-Yi
Simpson, Jim
Chen, Yong
Li, Jiang-Sheng
Ning, Hui-Sen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O5719 - O5721
[32] REACTION OF TERT-BUTOXY RADICALS WITH 2,6-DI-TERT-BUTYL-4-METHYLPHENOL AND 2,6-DI-TERT-BUTYLPHENOL
INGOLD, KU
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1963, 41 (11): : 2807 - &
[33] The interaction of N,N′-bis(2,6-dimethylphenyl)imidazol-2-ylidene with o-benzosemiquinonato zinc(II) and indium(III) complexes
Ilyakina, Ekaterina V.
Poddel'sky, Andrey I.
Piskunov, Alexandr V.
Fukin, Georgii K.
Bogomyakov, Artem S.
Cherkasov, Vladimir K.
Abakumov, Gleb A.
NEW JOURNAL OF CHEMISTRY, 2012, 36 (10) : 1944 - 1948
[34] REACTIONS OF THE 2,6-DI-TERT.-BUTYL-4-(N-TERT.-BUTYLNITRONO)-PHENOXYL RADICAL
SCHULZ, M
BACH, B
REINHARDT, M
JOURNAL FUR PRAKTISCHE CHEMIE, 1984, 326 (04): : 579 - 587
[35] 2,6-Di-tert-butyl-4-[(N-methylanilino)methyl]phenol
Zeng, Tao
Sun, Ju-Feng
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O410 - U2063
[36] THE CHLORINATION OF 2-TERT-BUTYL-4,6-DIMETHYLPHENOL AND 2,6-DI-TERT-BUTYL-4-METHYLPHENOL - THE FORMATION OF 5,6-DICHLORO-4-METHYLENECYCLOHEX-2-ENONES
HARTSHORN, MP
JUDD, MC
ROBINSON, WT
AUSTRALIAN JOURNAL OF CHEMISTRY, 1986, 39 (12) : 2121 - 2143
[37] OXIDATION OF HINDERED PHENOLS .5. THE 2,6-DI-TERT-BUTYL-4-ISOPROPYL AND 2,6-DI-TERT-BUTYL-4-SEC-BUTYLPHENOXY RADICALS
COOK, CD
NORCROSS, BE
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (15) : 3797 - 3799
[38] Crystal structure of 4-tert-butyl-1-(2,6-dimethylphenyl)-1H-1,2,3-triazole, C14H19N3
Yerima, Iliya B.
Zamisa, Sizwe J.
Bala, Muhammad D.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (04): : 625 - 627
[39] A novel five-coordinate manganese(III) complex with 4,6-di-tert-butyl-N-(2, 6-di-iso-propylphenyl)-1,2-iminobenzoquinone: Reversible interaction with dioxygen
Abakumov G.A.
Cherkasov V.K.
Poddel'sky A.I.
Bubnov M.P.
Abakumova L.G.
Fukin G.K.
Doklady Chemistry, 2004, 399 (1-3) : 207 - 210
[40] BUTYLHYDROXYTOLUENES . 2,6-DI-TERT-BUTYL-4-METHYL PHENOL
不详
ANNALES PHARMACEUTIQUES FRANCAISES, 1968, 26 (01): : 93 - &

← 1 2 3 4 5 →