Candy-like heterojunction nanocomposite of WO3/Fe2O3-based semiconductor gas sensor for the detection of triethylamine

被引:28
|
作者
Qu, Zhengfang [1 ,2 ]
Li, Yunxiao [1 ]
Xu, Rui [1 ]
Li, Chenchen [2 ]
Wang, Huan [2 ]
Wang, Huabin [1 ]
Zhang, Yong [1 ]
Wei, Qin [2 ]
机构
[1] Yunnan Normal Univ, Prov Key Lab Rural Energy Engn Yunnan, Kunming 650500, Peoples R China
[2] Univ Jinan, Collaborat Innovat Ctr Green Chem Mfg & Accurate D, Sch Chem & Chem Engn, Key Lab Interfacial React & Sensing Analysis Univ, Jinan 250022, Peoples R China
基金
中国国家自然科学基金;
关键词
Triethylamine; Gas sensor; Fe2O3; nanocomposite; Controllable preparation; Functional WO3 nanocomposite; SENSING MECHANISM; WO3; CHROMATOGRAPHY; PERFORMANCE; NANOSHEETS; DESIGN; LAYER;
D O I
10.1007/s00604-023-05699-x
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A highly efficient gas sensor for the detection of triethylamine based on candy-like WO3/Fe2O3 nanocomposite was prepared. The control of morphology and sensing performance of n-n heterojunction WO3/Fe2O3 nanocomposites were successfully achieved by the modulation of Fe element content. When the ratio of Fe to W is 0.4, the candy-like nanocomposite of WO3/Fe2O3 with great performance is obtained. It is interesting that the candy-like nanocomposite of WO3/Fe2O3 with a large specific surface area exhibits better selectivity and sensitivity for sensing TEA gases at a lower operating temperature (260 & DEG;C) compared with the gas sensor prepared by using WO3 alone. To verify the feasibility, the sensing mechanism was investigated and real sample tests were conducted and discussed. Finally, a TEA gas sensor with low limit of detection, short response/recovery time (15/162 s), and high sensitivity was developed. In addition, the prepared gas sensor has satisfactory stability and selectivity and has practical application value.
引用
收藏
页数:9
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