Candy-like heterojunction nanocomposite of WO3/Fe2O3-based semiconductor gas sensor for the detection of triethylamine

被引:28
|
作者
Qu, Zhengfang [1 ,2 ]
Li, Yunxiao [1 ]
Xu, Rui [1 ]
Li, Chenchen [2 ]
Wang, Huan [2 ]
Wang, Huabin [1 ]
Zhang, Yong [1 ]
Wei, Qin [2 ]
机构
[1] Yunnan Normal Univ, Prov Key Lab Rural Energy Engn Yunnan, Kunming 650500, Peoples R China
[2] Univ Jinan, Collaborat Innovat Ctr Green Chem Mfg & Accurate D, Sch Chem & Chem Engn, Key Lab Interfacial React & Sensing Analysis Univ, Jinan 250022, Peoples R China
基金
中国国家自然科学基金;
关键词
Triethylamine; Gas sensor; Fe2O3; nanocomposite; Controllable preparation; Functional WO3 nanocomposite; SENSING MECHANISM; WO3; CHROMATOGRAPHY; PERFORMANCE; NANOSHEETS; DESIGN; LAYER;
D O I
10.1007/s00604-023-05699-x
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A highly efficient gas sensor for the detection of triethylamine based on candy-like WO3/Fe2O3 nanocomposite was prepared. The control of morphology and sensing performance of n-n heterojunction WO3/Fe2O3 nanocomposites were successfully achieved by the modulation of Fe element content. When the ratio of Fe to W is 0.4, the candy-like nanocomposite of WO3/Fe2O3 with great performance is obtained. It is interesting that the candy-like nanocomposite of WO3/Fe2O3 with a large specific surface area exhibits better selectivity and sensitivity for sensing TEA gases at a lower operating temperature (260 & DEG;C) compared with the gas sensor prepared by using WO3 alone. To verify the feasibility, the sensing mechanism was investigated and real sample tests were conducted and discussed. Finally, a TEA gas sensor with low limit of detection, short response/recovery time (15/162 s), and high sensitivity was developed. In addition, the prepared gas sensor has satisfactory stability and selectivity and has practical application value.
引用
收藏
页数:9
相关论文
共 50 条
  • [1] Candy-like heterojunction nanocomposite of WO3/Fe2O3-based semiconductor gas sensor for the detection of triethylamine
    Zhengfang Qu
    Yunxiao Li
    Rui Xu
    Chenchen Li
    Huan Wang
    Huabin Wang
    Yong Zhang
    Qin Wei
    Microchimica Acta, 2023, 190
  • [2] γ-Fe2O3-Based MEMS Gas Sensor for Propane Detection
    Gao, Xiang
    Chen, Ying
    Xu, Pengcheng
    Zheng, Dan
    Li, Xinxin
    ELECTRONICS, 2025, 14 (05):
  • [3] Semiconductor-Type Triethylamine Sensor for Food Detection Based on WO3 Nanomaterials
    Yang, Yina
    Liu, Jin
    Zheng, Xiaohong
    Ye, Chunlin
    Wan, Bo
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2023, 170 (11)
  • [4] Superior triethylamine detection at room temperature by {-112} faceted WO3 gas sensor
    Gui, Yanghai
    Tian, Kuan
    Liu, Junxian
    Yang, Lele
    Zhang, Hongzhong
    Wang, Yun
    JOURNAL OF HAZARDOUS MATERIALS, 2019, 380
  • [5] High performance ammonia gas detection based on TiO2/WO3•H2O heterojunction sensor
    Cheng, Cao
    Zhang, Hongyan
    Li, Fan
    Yu, Shuguo
    Chen, Yan
    MATERIALS CHEMISTRY AND PHYSICS, 2021, 273
  • [6] High Sensitive Triethylamine Gas Sensor Based on C@WS2/WO3 Composite
    Yan, Shuang
    Xie, Penghui
    Chi, Chunyu
    Zhang, Haoyu
    Zhao, Junyu
    Hao, Hongshun
    NANO, 2024,
  • [7] Nanocomposite based on semiconductor oxides SnO2/WO3
    Rumyntseva, MN
    Boulova, MN
    Chareev, DA
    Ryabova, LI
    Akimov, BA
    Gaskov, AM
    NANOPHASE AND NANOCOMPOSITE MATERIALS IV, 2002, 703 : 349 - 354
  • [8] Photocatalytic activity of WO3/Fe2O3 nanocomposite photoanode
    Memar, Amir
    Phan, Chi M.
    Tade, Moses O.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (28) : 8642 - 8649
  • [9] Highly sensitive triethylamine gas sensor by Pt-loaded p-n heterojunction Co3O4/WO3
    Song, Zhenlin
    Zeng, Jiyang
    Zi, Baoye
    Chen, Fengying
    Zhang, Yumin
    Zhang, Genlin
    Zhu, Zhongqi
    Zhang, Jin
    Liu, Qingju
    NANOTECHNOLOGY, 2023, 34 (04)
  • [10] Gas Sensor Based on Flower-like NiO Modified with WO3 Nanoparticles for NO2 Detection
    Li, Qianyun
    Zhang, Peng
    Ning, Tengge
    Sun, Yushu
    Ren, Qianqian
    Xu, Manzhang
    Zhao, Xinya
    Luo, Xiaoli
    Zhai, Chunxue
    Yan, Junfeng
    Ma, Xiaolong
    Li, Qiang
    Wu, Zhao
    ACS APPLIED NANO MATERIALS, 2024, 7 (07) : 7856 - 7864