Photodeposition of molybdenum sulfide on MTiO3 (M: Ba, Sr) perovskites for photocatalytic hydrogen evolution

被引：11
作者：
Kuru, Talha [1 ,4 ]
Yanalak, Gizem [2 ]
Sarilmaz, Adem [3 ]
Aslan, Emre [2 ]
Keles, Ali [4 ]
Genc, Munevver Tuna [1 ]
Ozel, Faruk [3 ]
Patir, Imren Hatay [1 ]
Kus, Mahmut [5 ]
Ersoz, Mustafa [6 ]
机构：
[1] Selcuk Univ, Dept Biotechnol, TR-42030 Konya, Turkiye
[2] Selcuk Univ, Dept Biochem, TR-42030 Konya, Turkiye
[3] Karamanoglu Mehmetbey Univ, Dept Met & Mat Engn, TR-70200 Karaman, Turkiye
[4] GKE Energy R&D Ctr, TR-48200 Mugla, Turkiye
[5] Konya Tech Univ, Dept Chem Engn, TR-42075 Konya, Turkiye
[6] Selcuk Univ, Dept Chem, TR-42030 Konya, Turkiye
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2023年 / 436卷
关键词：
Hydrogen evolution; Photocatalyst; Photodeposition; Perovskites; Titanates; AMORPHOUS MOSX; H-2; PRODUCTION; NANOPARTICLES; COCATALYST; EOSIN; CDS; TITANATE; SRTIO3; FE; NI;
D O I：
10.1016/j.jphotochem.2022.114375
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Photocatalytic hydrogen evolution using by semiconductor materials have been studied effectively by converting solar energy into the chemical energy. Perovskite-based materials have been widely used as semiconductor catalysts for the photocatalytic hydrogen production. Herein, molybdenum sulfide photodeposited onto MTiO3 (M: Ba, Sr) perovskites (MTiO3/MoSx) have been investigated on the photocatalytic hydrogen evolution under solar light irradiation in the presence of triethanolamine (TEOA) and eosin Y (EY) as an electron donor and photosensitizer, respectively. Compared to pristine MTiO3, BaTiO3/MoSx and SrTiO3/MoSx show a remarkable improvement in the hydrogen production efficiency and stability. Photocatalytic hydrogen evolution activities found in the order of SrTiO3/MoSx > BaTiO3/MoSx > MoSx > SrTiO3 > BaTiO3. In addition, photocatalytic hydrogen activity of SrTiO3/Pt was evaluated for comparison with SrTiO3/MoSx under the same conditions and SrTiO3/MoSx produced higher hydrogen activity than SrTiO3/Pt due to the high active sites created by MoSx on the catalyst surface which is originated from Mo-S and S-S bonds.
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页数：6
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