Stability of Y2O3:Tm,Yb phosphor thin films during cathodoluminescence and upconversion

被引：5
作者：
Hasabeldaim, Emad [1 ]
Swart, H. C. [1 ]
Kroon, R. E. [1 ]
机构：
[1] Univ Free State, Dept Phys, ZA-9300 Bloemfontein, South Africa
来源：
PHYSICA B-CONDENSED MATTER | 2023年 / 671卷
基金：
新加坡国家研究基金会;
关键词：
Upconversion; Cathodoluminescence; Stability; AES; XPS; Y2O3:Tm3+; Yb3+; LUMINESCENCE; ELECTROLUMINESCENCE; PHOTOLUMINESCENCE; NANOPHOSPHORS; EMISSION; BLUE;
D O I：
10.1016/j.physb.2023.415417
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
An Y2O3:Tm,Yb thin film was synthesized by the sol-gel method using spin coating. X-ray powder diffraction revealed the formation of a Y2O3 cubic phase. The cathodoluminescence and upconversion photoluminescence of the film were investigated, including assessment of emission stability. Auger electron spectroscopy was used to monitor its chemical state concurrently with the cathodoluminescence intensity using the same electron beam. Auger peaks associated with carbon, yttrium and oxygen were detected and their Auger peak-to-peak heights indicated that carbon was removed from the surface during the initial stage of degradation, whereas yttrium and oxygen remained almost unchanged. The cathodoluminescence degradation of the Tm emissions at 457 nm and 975 nm exhibited a continuous decline until the electron dose was about 100 C/cm(2) and then stabilized. The upconversion photoluminescence intensity of the Tm emission at 488 nm remained stable for a period of 28 h and did not exhibit degradation.
引用
收藏
页数：7
相关论文
共 34 条
  • [1] Er:Y2O3 and Nd:Y2O3 Nanoparticles: Synthesis, Pegylation, Characterization and Study of Their Luminescence Properties[J]. Chiechio, Regina Maria;Battaglia, Rosalia;Caponnetto, Angela;Butera, Ester;Franzo, Giorgia;Reitano, Riccardo;Purrello, Michele;Ragusa, Marco;Barbagallo, Davide;Barbagallo, Cristina;Di Pietro, Cinzia;Marchi, Valerie;Lo Faro, Maria Jose;Contino, Annalinda;Maccarrone, Giuseppe;Musumeci, Paolo. CHEMOSENSORS, 2023(01)
  • [2] The role of Li+ in the upconversion emission enhancement of (YYbEr)2O3 nanoparticles[J]. Debasu, Mengistie L.;Riedl, Jesse C.;Rocha, J.;Carlos, Luis D. NANOSCALE, 2018(33)
  • [3] In situ transmission electron microscopy observation of ZnO polar and non-polar surfaces structure evolution under electron beam irradiation[J]. Ding, Yong;Pradel, Ken C.;Wang, Zhong Lin. JOURNAL OF APPLIED PHYSICS, 2016(01)
  • [4] Visible and mid-infrared spectral emissions and radiative rates calculations of Tm3+ doped BBLC glass[J]. El-Maaref, A. A.;Wahab, E. A. Abdel;Shaaban, Kh S.;Abdelawwad, M.;Koubisy, M. S., I;Boercsoek, J.;Yousef, El Sayed. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2020
  • [5] Y2O3:Tm,Yb nanophosphors for correlative upconversion luminescence and cathodoluminescence imaging[J]. Fukushima, Shoichiro;Furukawa, Taichi;Niioka, Hirohiko;Ichimiya, Masayoshi;Miyake, Jun;Ashida, Masaaki;Araki, Tsutomu;Hashimoto, Mamoru. MICRON, 2014
  • [6] Electroluminescence and photoluminescence of rare earth (Eu,Tb) doped Y2O3 nanophosphor[J]. Gupta, Anuradha;Brahme, Nameeta;Bisen, Durga Prasad. JOURNAL OF LUMINESCENCE, 2014
  • [7] Blue, green and red cathodoluminescence of Y2O3 phosphor films prepared by spray pyrolysis[J]. Hao, JH;Studenikin, SA;Cocivera, M. JOURNAL OF LUMINESCENCE, 2001(04)
  • [8] Structural, optical and photoluminescence properties of Eu doped ZnO thin films prepared by spin coating[J]. Hasabeldaim, E.;Ntwaeaborwa, O. M.;Kroon, R. E.;Swart, H. C. JOURNAL OF MOLECULAR STRUCTURE, 2019
  • [9] Surface characterization and cathodoluminescence degradation of ZnO thin films[J]. Hasabeldaim, E.;Ntwaeaborwa, O. M.;Kroon, R. E.;Craciun, V.;Coetsee, E.;Swart, H. C. APPLIED SURFACE SCIENCE, 2017
  • [10] Luminescence and stability of Tb doped CaF2 nanoparticles[J]. Hasabeldaim, E. H. H.;Swart, H. C.;Kroon, R. E. RSC ADVANCES, 2023(08)
1234