Evaluation of efficiency of Wheat straw nanocellulose as nanoadsorbent for the removal of divalent copper, lead and zinc from aqueous solution

被引:12
作者
Kaur, Mandeep [1 ]
Pal, Jitender [1 ]
机构
[1] Guru Jambheshwar Univ Sci & Technol, Dept Environm Sci & Engn, Hisar 125001, Haryana, India
来源
CARBOHYDRATE POLYMER TECHNOLOGIES AND APPLICATIONS | 2023年 / 6卷
关键词
Nanoadsorbent; Heavy metal removal; Adsorption kinetics; Isotherms; Thermodynamic analysis; Reusability; HEAVY-METAL IONS; CELLULOSE; ADSORPTION; ADSORBENTS; ZN(II);
D O I
10.1016/j.carpta.2023.100350
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Novel nanocellulose (cellulosic carbohydrate polymer) embedded with Wheat straw was synthesized, characterized and examined as nanoadsorbent for the removal of copper, lead and zinc metals from aqueous solution through batch mode. The effects of pH, dose, contact time, temperature and synchronous cations on the amount of Cu (II), Pb (II) and Zn (II) adsorbed have been probed. The desirable pH was 8 and nanoadsorbent dose was 0.6 g/50 mL in the adsorption study. The removal efficiencies of Cu (II), Pb (II) and Zn (II) were 88.75%, 81.18%, 86.84% respectively. Adsorption kinetic study was employed to analyze experimental data and adsorption process followed pseudo second order kinetic model. Langmuir, Freundlich, Temkin and Redlich-Peterson isotherm models were used to indicate the adsorption of Cu (II), Pb (II) and Zn (II) on WSN and thermodynamic study affirmed that adsorption process was endothermic and spontaneous. AFM indicated size and morphology and attachment of functional groups on WSN were examined by FTIR. The results confided that adsorption is economically competent method for removing Cu (II), Pb (II) and Zn (II) and WSN is anticipative owing to its ease and low cost of regeneration
引用
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页数:12
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共 65 条
[11]   Cellulose nanowhiskers extracted from TEMPO-oxidized jute fibers [J].
Cao, Xinwang ;
Ding, Bin ;
Yu, Jianyong ;
Al-Deyab, Salem S. .
CARBOHYDRATE POLYMERS, 2012, 90 (02) :1075-1080
[12]   Adsorption capability of brewed tea waste in waters containing toxic lead(II), cadmium (II), nickel (II), and zinc(II) heavy metal ions [J].
Celebi, Hakan ;
Gok, Gulden ;
Gok, Oguzhan .
SCIENTIFIC REPORTS, 2020, 10 (01)
[13]   Isolation and characterization of cellulose nanofibrils from arecanut husk fibre [J].
Chandra, Julie C. S. ;
George, Neena ;
Narayanankutty, Sunil K. .
CARBOHYDRATE POLYMERS, 2016, 142 :158-166
[14]   A novel method for the synthesis of cellulose nanofibril whiskers from banana fibers and characterization [J].
Cherian, Bibin Mathew ;
Pothan, Laly A. ;
Nguyen-Chung, Tham ;
Mennig, Guenter ;
Kottaisamy, M. ;
Thomas, Sabu .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2008, 56 (14) :5617-5627
[15]   Recent studies in adsorption of Pb(II), Zn(II) and Co(II) using conventional and modified materials:a review [J].
Corda, Nikita ;
Kini, M. Srinivas .
SEPARATION SCIENCE AND TECHNOLOGY, 2020, 55 (15) :2679-2698
[16]   Removal of Heavy Metal Ions Using Modified Celluloses Prepared from Pineapple Leaf Fiber [J].
Daochalermwong, Amphol ;
Chanka, Napassorn ;
Songsrirote, Kriangsak ;
Dittanet, Peerapan ;
Niamnuy, Chalida ;
Seubsai, Anusorn .
ACS OMEGA, 2020, 5 (10) :5285-5296
[17]   Utilization of various lignocellulosic biomass for the production of nanocellulose: a comparative study [J].
Deepa, B. ;
Abraham, Eldho ;
Cordeiro, Nereida ;
Mozetic, Miran ;
Mathew, Aji P. ;
Oksman, Kristiina ;
Faria, Marisa ;
Thomas, Sabu ;
Pothan, Laly A. .
CELLULOSE, 2015, 22 (02) :1075-1090
[18]   Removal of Zn(II), Mn(II) and Cu(II) by adsorption onto banana stalk biochar: adsorption process and mechanisms [J].
Deng, Hua ;
Li, Qiuyan ;
Huang, Meijia ;
Li, Anyu ;
Zhang, Junyu ;
Li, Yafen ;
Li, Shuangli ;
Kang, Caiyan ;
Mo, Weiming .
WATER SCIENCE AND TECHNOLOGY, 2020, 82 (12) :2962-2974
[19]   ZnO Nanoadsorbents: A potent material for removal of heavy metal ions from wastewater [J].
Dhiman, Vikas ;
Kondal, Neha .
COLLOID AND INTERFACE SCIENCE COMMUNICATIONS, 2021, 41
[20]   Cellulose microfibres produced from banana plant wastes: Isolation and characterization [J].
Elanthikkal, Silviya ;
Gopalakrishnapanicker, Unnikrishnan ;
Varghese, Soney ;
Guthrie, James T. .
CARBOHYDRATE POLYMERS, 2010, 80 (03) :852-859