Photoinduced Pd-Catalyzed Dearomative 2,5-Difunctionalizition of Furans via Cascade C-C/C-O Bond Formation

被引：8
作者：
Long, Fen [1 ]
Jiang, Kai [1 ]
Song, Weiwei [1 ]
Luo, Wenkun [2 ]
Yin, Biaolin [1 ]
机构：
[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China
[2] Changsha Univ Sci & Technol, Sch Chem & Chem Engn, Hunan Prov Key Lab Cytochem, Changsha 410114, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 05期
基金：
中国国家自然科学基金;
关键词：
CHEMICALS; REARRANGEMENT; BIOMASS; INDOLES; RING;
D O I：
10.1021/acs.orglett.3c04345
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report an efficient and mild approach for radical dearomatization via photoinduced palladium-catalyzed reaction of three components (i.e., furans, alcohols, and bromoalkanes). In this strategy, various functionalized spiro-heterocycles were prepared from furans in one step via cascade C-C/C-O bond formation under redox neutral conditions.
引用
收藏
页码：1083 / 1087
页数：5
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