First identification of a new molecule involved in the fresh mushroom off-flavor in wines: 1-hydroxyoctan-3-one

被引:12
作者
Delcros, Lea [1 ,2 ,3 ]
Costis, Arnaud [3 ]
Le Guerneve, Christine [3 ]
Collas, Sylvie [2 ]
Herve, Marion [1 ]
Roland, Aurelie [3 ]
机构
[1] MHCS, Epernay, France
[2] Comite Champagne, Epernay, France
[3] Univ Montpellier, Inst Agro, UMR SPO, INRAE, Montpellier, France
关键词
1-Hydroxyoctan-3-one; Fresh mushroom off-flavor; Wine; Must; Volatiles compound; VOLATILE COMPOUNDS; CHARDONNAY GRAPES; UNCINULA-NECATOR; LINOLEIC-ACID; AROMA; 1-OCTEN-3-OL; 10-HYDROPEROXIDE; PENICILLIUM; IMPACT; ROT;
D O I
10.1016/j.foodchem.2023.135678
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The fresh mushrooms off-flavor (FMOff) has been appearing in wines since the 2000 s; the C8 compounds, 1-octen-3-one, 1-octen-3-ol and 3-octanol are involved in this specific taint, yet they alone do not fully explain its occurrence. The objective of this work was to identify by GC-MS new FMOff markers in contaminated matrices, to correlate compound levels with wine sensory characterization and to determine the sensory attri-butes of 1-hydroxyoctan-3-one, a new candidate involved in FMOff. In practice, grape musts were artificially contaminated with Crustomyces subabruptus, and fermented to obtain tainted wines. GC-MS analysis of contaminated musts and wines revealed the presence of 1-hydroxyoctan-3-one only in contaminated musts, and not in the healthy control. In a selection of 16 wines affected by FMOff, the level of 1-hydroxyoctan-3-one correlated significantly (r2 = 0.86) with sensory analysis scores. Finally, 1-hydroxyoctan-3-one was synthe-sized and found to generate a fresh mushroom aroma in a wine matrix.
引用
收藏
页数:10
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