Experimental methodologies to perform accelerated deactivation studies of hydrotreating catalysts

被引:13
作者
Morales-Leal, Francisco Jose [1 ]
Ancheyta, Jorge [1 ]
Torres-Mancera, Pablo [1 ]
Alonso, Fernando [1 ]
机构
[1] Inst Mexicano Petr, Eje Cent Lazaro Cardenas Norte 152, Mexico City 07730, Mexico
关键词
Hydrotreating catalyst; Accelerated deactivation; Coke and metal deposition; HYDROPROCESSING MULTICATALYST DEACTIVATION; INITIAL COKE DEPOSITION; PILOT-PLANT; FEED HYDROTREATMENT; OIL; REACTOR; HYDRODESULFURIZATION; COMO/AL2O3; CRACKING; SPENT;
D O I
10.1016/j.fuel.2022.126074
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A comprehensive review of the scientific literature over the last two decades is conducted to have a clear un-derstanding of the factors that accelerate the deactivation of hydrotreating (HDT) catalysts. The reported experimental methodologies employed at laboratory and pilot plant scales focused on achieving accelerated deactivation of HDT catalysts are reviewed and discussed. The different methodologies attempt to reproduce industrial long-term catalysts deactivation by using different operating conditions (mainly high reaction tem-perature and low H2-to-oil ratio) or feedstock with high content of compounds that cause coke and metal deposition, in short-term experiments.
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页数:15
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