The regulation of electro-optical properties and polymer morphology of polymer-dispersed liquid crystal containing POSS microstructure by click chemistry and UV intensity

被引:0
作者
Zhang, Yongming [1 ]
Yue, Hongjia [1 ]
Liu, Jie [1 ]
Gao, Shiyan [1 ]
Guo, Zhun [1 ]
Gao, Jianjing [1 ]
Ma, Cheng [1 ]
Zhao, Yuzhen [1 ]
He, Zemin [1 ]
机构
[1] Xijing Univ, Sch Elect Informat, Xian Key Lab Adv Photoelect Mat & Energy Convers, Xian 710123, Peoples R China
关键词
Click chemistry; electro-optical properties; polymer-dispersed liquid crystals (PDLCs); polymer morphology; POSS-KH570; UV light intensity; HYBRID MATERIALS; LIGHT; PERFORMANCE; NETWORK;
D O I
10.1080/15421406.2022.2129287
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, the thiol-ene click reaction was used to prepare polymer-dispersed liquid crystal films by a photo-initiated polymerization reaction. Different content of DET was introduced into the polymer matrix to enhance the electro-optical performance of PDLC. Our results showed that the introducing of DET significantly improved the electro-optical properties of PDLC. The SEM results showed that larger and uniform pores were observed with increasing DET content. And it was found that an increase in UV intensity resulted in a continuous decrease in T-off and an increase in CR for weakening the anchoring effect of the polymer matrix.
引用
收藏
页码:46 / 57
页数:12
相关论文
共 36 条
[1]   The Effect of UV Intensities and Curing Time on Polymer Dispersed Liquid Crystal (PDLC) Display: A Detailed Analysis Study [J].
Ahmad, Farzana ;
Jamil, Muhammad ;
Lee, Jin Woo ;
Kim, Seo Rok ;
Jeon, Young Jae .
ELECTRONIC MATERIALS LETTERS, 2016, 12 (05) :685-692
[2]   Polyhedral Oligomeric Silsesquioxane (POSS)-Containing Polymer Nanocomposites [J].
Ayandele, Ebunoluwa ;
Sarkar, Biswajit ;
Alexandridis, Paschalis .
NANOMATERIALS, 2012, 2 (04) :445-475
[3]   Polymer-Dispersed Liquid Crystals: Progress in Preparation, Investigation, and Application [J].
Bronnikov, Sergei ;
Kostromin, Sergei ;
Zuev, Vjacheslav .
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2013, 52 (12) :1718-1735
[4]   Photoinitiation and Inhibition under Monochromatic Green Light for Storage of Colored 3D Images in Holographic Polymer-Dispersed Liquid Crystals [J].
Chen, Guannan ;
Ni, Mingli ;
Peng, Haiyan ;
Huang, Feihong ;
Liao, Yonggui ;
Wane, Mingkui ;
Zhu, Jintao ;
Roy, V. A. L. ;
Xie, Xiaolin .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (02) :1810-1819
[5]   2D/3D switchable displays through PDLC reverse mode parallax barrier [J].
Chidichimo, Giuseppe ;
Beneduci, Amerigo ;
Maltese, Vito ;
Cospito, Sante ;
Tursi, Antonio ;
Tassini, Paolo ;
Pandolfi, Giuseppe .
LIQUID CRYSTALS, 2018, 45 (13-15) :2132-2138
[6]   Functional polypeptide and hybrid materials: Precision synthesis via α-amino acid N-carboxyanhydride polymerization and emerging biomedical applications [J].
Deng, Chao ;
Wu, Jintian ;
Cheng, Ru ;
Meng, Fenghua ;
Klok, Harm-Anton ;
Zhong, Zhiyuan .
PROGRESS IN POLYMER SCIENCE, 2014, 39 (02) :330-364
[7]   Study on the morphologies and electro-optical properties of cyano-phenyl-ester liquid crystals/polymer composite films prepared by a stepwise polymerisation [J].
Gao, Hongqi ;
Zhang, Shuaifeng ;
Saeed, Mohsin Hassan ;
Chen, Gang ;
Lin, Haonan ;
Huang, Junyi ;
Zhang, Lanying ;
Wang, Qian ;
Cao, Hui .
LIQUID CRYSTALS, 2020, 47 (10) :1497-1506
[8]   The regulation of electric-optical properties of polymer-dispersed liquid crystals via implantation of polyhedral oligomeric silsesquioxane (POSS) microstructure [J].
He, Zemin ;
Yu, Ping ;
Zhao, Yuzhen ;
Yang, Qing ;
Zhao, Yang ;
Zhang, Huimin ;
Zi, Shuai ;
Miao, Zongcheng ;
Zhang, Haiquan ;
Shen, Wenbo .
LIQUID CRYSTALS, 2022, 49 (02) :240-247
[9]   Evaluation of thermal performance for a smart switchable adaptive polymer dispersed liquid crystal (PDLC) glazing [J].
Hemaida, Abdulmohsin ;
Ghosh, Aritra ;
Sundaram, Senthilarasu ;
Mallick, Tapas K. .
SOLAR ENERGY, 2020, 195 :185-193
[10]   ELECTROOPTIC RESPONSE OF POLYMER DISPERSED LIQUID-CRYSTAL FILMS [J].
JAIN, SC ;
ROUT, DK .
JOURNAL OF APPLIED PHYSICS, 1991, 70 (11) :6988-6992