Selective Oxidation of Primary Alcohols to Carboxylic Acids Using Lacunary Polyoxometalates Catalysts and Hydrogen Peroxide

被引：1

作者：

Yu, Feng-Li ^{[1
]}

Liu, Min-Xue ^{[1
]}

Yuan, Bing ^{[1
]}

Xie, Cong-Xia ^{[1
]}

Yu, Shi-Tao ^{[2
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China

[2] Qingdao Univ Sci & Technol, Coll Chem Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China

来源：

CATALYSIS LETTERS | 2023年 / 153卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Aliphatic acids; Primary alcohols; Selective oxidation; Lacunary polyoxometalates; Propionic acid; AEROBIC OXIDATION; PROPIONIC-ACID; BENZYL ALCOHOL; ALDEHYDES; POLYOXOTUNGSTATES; TEMPERATURE; EFFICIENT;

D O I：

10.1007/s10562-022-04105-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first organic-inorganic lacunary polyoxometalate catalytic oxidation system with H2O2 as an oxidant for the preparation of aliphatic carboxylic acids from primary alcohols has been developed. This new catalytic system not only exhibits good catalytic activity with high selectivity toward acids, but also satisfactorily resolves the separation of the catalyst for reuse.

引用

页码：1738 / 1742

页数：5

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